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Merck
CN

678015

4,7-Dichloro-1,10-phenanthroline

97%, solid

Synonym(s):

4,7-Dichloro-o-phenanthroline

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About This Item

Empirical Formula (Hill Notation):
C12H6Cl2N2
CAS Number:
5394-23-0
Molecular Weight:
249.10
UNSPSC Code:
12352300
PubChem Substance ID:
24885412
NACRES:
NA.22
MDL number:
MFCD00233882

Key Documents

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Product Name

4,7-Dichloro-1,10-phenanthroline, 97%

SMILES string

Clc1ccnc2c1ccc3c(Cl)ccnc23

InChI

1S/C12H6Cl2N2/c13-9-3-5-15-11-7(9)1-2-8-10(14)4-6-16-12(8)11/h1-6H

InChI key

GIEQBYJCGYHHSU-UHFFFAOYSA-N

assay

97%

form

solid

mp

243-247 °C

Quality Level

100

Related Categories

pictograms

Skull and crossbonesCorrosion
GHS06,GHS05

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCN1627
MKCB6564
MKBK3020V
MKBD4051
59098PJ

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Ryan A Altman et al.
Organic letters, 8(13), 2779-2782 (2006-06-16)
[reaction: see text] 4,7-Dimethoxy-1,10-phenanthroline (L) was found to be an efficient ligand for the copper-catalyzed N-arylation of imidazole with aryl iodides and bromides under mild conditions. A variety of hindered and functionalized imidazoles and aryl halides were transformed in good
Anna M Maroń et al.
Dalton transactions (Cambridge, England : 2003), 49(14), 4441-4453 (2020-03-18)
Three Re(i) carbonyl complexes [ReCl(CO)3(Ln)] bearing 2,2'-bipyridine, 2,2':6',2''-terpyridine, and 1,10-phenanthroline functionalized with diphenylamine/or triphenylamine units (L1-L3) were synthesized to explore the impact of highly electron donating units appended to the imine ligand on the thermal and optoelectronic properties of Re(i)

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