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Key Documents

677922

Sigma-Aldrich

[Bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I) (2:1) toluene adduct

Synonym(s):

[Bis(trifluoromethanesulfonyl)imidate](PPh3)gold(I) (2:1) toluene adduct

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5 G
¥897.27
25 G
¥1,463.25

¥897.27


Available to ship on2025年4月25日Details


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5 G
¥897.27
25 G
¥1,463.25

About This Item

Linear Formula:
(C20H15AuF6NO4PS2) 2 · C7H8
Molecular Weight:
1570.93
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

¥897.27


Available to ship on2025年4月25日Details


Request a Bulk Order

form

solid

Quality Level

reaction suitability

core: gold
reagent type: catalyst

SMILES string

[Au]N(S(=O)(C(F)(F)F)=O)S(=O)(C(F)(F)F)=O.[Au]N(S(=O)(C(F)(F)F)=O)S(=O)(C(F)(F)F)=O.CC1=CC=CC=C1.P(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.P(C5=CC=CC=C5)(C6=CC=CC=C6)C7=CC=CC=C7

InChI

1S/2C18H15P.C7H8.2C2F6NO4S2.2Au/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;2*3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;;/h2*1-15H;2-6H,1H3;;;;/q;;;2*-1;2*+1

InChI key

SIVCTOVPPFSWEF-UHFFFAOYSA-N

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This Item
FHIFINROEHIFIPROEHIFIPNRO
technique(s)

PCR: suitable

technique(s)

PCR: suitable

technique(s)

PCR: suitable

technique(s)

PCR: suitable

usage

sufficient for ≤1,000 reactions (03553361001)

usage

sufficient for ≤200 reactions (04738292001), sufficient for ≤50 reactions (04738284001)

usage

sufficient for ≤2,500 reactions (03300234001), sufficient for 2500 reactions, sufficient for ≤500 reactions (03300226001), sufficient for 500 reactions

usage

sufficient for ≤125 reactions (04743725001), sufficient for ≤500 reactions (04743733001)

feature

High Fidelity PCR

feature

-

feature

High Fidelity PCR, dNTPs included: no, hotstart: no

feature

High Fidelity PCR, dNTPs included, hotstart: no

packaging

pkg of 2,500 U (03553361001 [10 x 250 U])

packaging

pkg of 125 U (04738284001), pkg of 500 U (04738292001 [2 x 250 U])

packaging

pkg of 2,500 U (03300234001 [10x250 U]), pkg of 500 U (03300226001 [2x250 U])

packaging

pkg of 125 U (04743725001), pkg of 500 U (04743733001 [2x250 U])

manufacturer/tradename

Roche

manufacturer/tradename

Roche

manufacturer/tradename

Roche

manufacturer/tradename

Roche

concentration

5 unit/μL

concentration

-

concentration

-

concentration

50 U/mL (working concentration)

Application

[Bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I) (2:1) toluene adduct can be used as a catalyst in the 1,3-isomerisation of propargylic alcohols to enones via Meyer-Schuster rearrangement.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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