674575
MacMillan Imidazolidinone OrganoCatalysts Kit I
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UNSPSC Code:
12352005
eCl@ss:
32161000
NACRES:
NA.22
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General description
MacMillan imidazolidinone organocatalysts are metal-free chiral catalysts widely used in enantioselective organic transformations. These organocatalysts are non-toxic, low cost, and robust in simple reaction conditions because of their insensitivity to air and moisture.
Application
MacMillan Imidazolidinone organocatalysts can be used to catalyze various organocatalytic transformation reactions such as 1,3-dipolar cycloadditions, Diels–Alder reaction, Friedel-Crafts alkylations, α-chlorinations, α-fluorinations, and intramolecular Michael reactions to access a high level of enantioselective products. It can also be used in enantioselective photocatalytic reactions, hydride reduction, and Mukaiyama-Michael reaction.
Legal Information
U.S. Pat. 6,369,243 and related patents apply. For research purposes only.
Kit Components Also Available Separately
Product No.
Description
SDS
- 569763(5S)-(−)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinone monohydrochloride, 97% 500 mgSDS
- 661902(S)-(+)-2-(tert-Butyl)-3-methyl-4-imidazolidinone trifluoroacetic acid, 96% 500 mgSDS
- 663085(5S)-(−)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinone dichloroacetic acid, 97% 500 mgSDS
- 663107(2S,5S)-(−)-2-tert-Butyl-3-methyl-5-benzyl-4-imidazolidinone, 97% 500 mgSDS
- 668540(2S,5S)-(–)-5-Benzyl-3-methyl-2-(5-methyl-2-furyl)-4-imidazolidinone, 95% 250 mgSDS
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 3 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Regulatory Information
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Certificates of Analysis (COA)
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Find documentation for the products that you have recently purchased in the Document Library.
Recent Development of Recoverable MacMillan Catalyst in Asymmetric Organic Transformations
Singh S
Advanced Synthesis & Catalysis, 363(3), 629-656 (2021)
Recent Development of Recoverable MacMillan Catalyst in Asymmetric Organic Transformations
Singh S
advanced synthesis and catalysis, 363(3), 629-656 (2021)
Imidazolidinones as Asymmetric Organocatalysts
Sustainable Catalysis: Without Metals or Other Endangered Elements (2015)
Articles
Discover Professor David MacMillan's groundbreaking metal-free asymmetric catalysis using imidazolidinone-based organocatalysts for versatile transformations.
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