674575
MacMillan Imidazolidinone OrganoCatalysts Kit I
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About This Item
UNSPSC Code:
12352005
NACRES:
NA.22
eCl@ss:
32161000
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Application
MacMillan Imidazolidinone organocatalysts can be used to catalyze various organocatalytic transformation reactions such as 1,3-dipolar cycloadditions, Diels–Alder reaction, Friedel-Crafts alkylations, α-chlorinations, α-fluorinations, and intramolecular Michael reactions to access a high level of enantioselective products. It can also be used in enantioselective photocatalytic reactions, hydride reduction, and Mukaiyama-Michael reaction.
General description
MacMillan imidazolidinone organocatalysts are metal-free chiral catalysts widely used in enantioselective organic transformations. These organocatalysts are non-toxic, low cost, and robust in simple reaction conditions because of their insensitivity to air and moisture.
Legal Information
U.S. Pat. 6,369,243 and related patents apply. For research purposes only.
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Danger
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Hazard Classifications
Acute Tox. 3 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Recent Development of Recoverable MacMillan Catalyst in Asymmetric Organic Transformations
Singh S
advanced synthesis and catalysis, 363(3), 629-656 (2021)
Recent Development of Recoverable MacMillan Catalyst in Asymmetric Organic Transformations
Singh S
Advanced Synthesis & Catalysis, 363(3), 629-656 (2021)
Imidazolidinones as Asymmetric Organocatalysts
Sustainable Catalysis: Without Metals or Other Endangered Elements (2015)
Articles
Discover Professor David MacMillan's groundbreaking metal-free asymmetric catalysis using imidazolidinone-based organocatalysts for versatile transformations.
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