671444
1,3-Dimethylimidazolium dimethyl phosphate
≥98.0% (HPLC)
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Synonym(s):
[MMIM][DMP]
Empirical Formula (Hill Notation):
C7H15N2O4P
CAS Number:
Molecular Weight:
222.18
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
Quality Level
Assay
≥98.0% (HPLC)
impurities
≤1.0% water
SMILES string
COP([O-])(=O)OC.Cn1cc[n+](C)c1
InChI
1S/C5H9N2.C2H7O4P/c1-6-3-4-7(2)5-6;1-5-7(3,4)6-2/h3-5H,1-2H3;1-2H3,(H,3,4)/q+1;/p-1
InChI key
GSGLHYXFTXGIAQ-UHFFFAOYSA-M
Related Categories
General description
1,3-Dimethylimidazolium dimethyl phosphate is an imidazolium-based phosphoric ionic liquid that can be prepared by reacting 1-methylimidazole with trimethyl phosphate. The pretreatment of sugarcane bagasse with [MMIM][DMP] yields glucose and xylose via enzymatic saccharification.
Application
1,3-Dimethylimidazolium dimethyl phosphate ([MMIM][DMP]) can be used as a catalyst and a solvent for the preparation of ethyl 2-cyano-3-phenylpropenoate from benzaldehyde and ethyl cyanoacetate via Knoevenagel condensation. It can also be used to produce bioethanol from sugarcane bagasse by enzymatic hydrolysis.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Skin Corr. 1B
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Dialkylimidazolium dimethyl phosphates as solvents and catalysts for the Knoevenagel condensation reaction.
Zicmanis A and Anteina L.
Tetrahedron Letters, 55(12), 2027-2028 (2014)
Imidazolium dialkylphosphates-a class of versatile, halogen-free and hydrolytically stable ionic liquids.
Kuhlmann E, et al.
Green Chemistry, 9(3), 233-242 (2007)
Samaneh Bahrani et al.
Bioresource technology, 185, 411-415 (2015-03-26)
In this study, an imidazolium-based ionic liquid (IL), 1,3-dimethylimidazolium dimethyl phosphate ([Mmim][DMP]), was applied for pretreating sugarcane bagasse to produce bioethanol. The main goal of this study was to investigate the feasibility of bagasse pretreatment with this IL, and to
Extractive desulfurization of gasoline using imidazolium-based phosphoric ionic liquids.
Nie Y, et al.
Energy and Fuels, 20(5), 2083-2087 (2006)
Major improvement in the rate and yield of enzymatic saccharification of sugarcane bagasse via pretreatment with the ionic liquid 1-ethyl-3-methylimidazolium acetate ([Emim][Ac]).
da Silva ASA, et al.
Bioresource Technology, 102(22), 10505-10509 (2011)
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