Skip to Content
Merck
CN

667544

Lithium chloride solution

0.5 M in anhydrous tetrahydrofuran

Synonym(s):

Lithium chloride, Lithium monochloride

Sign In to View Organizational & Contract Pricing.

Select a Size

About This Item

Linear Formula:
LiCl
CAS Number:
7447-41-8
Molecular Weight:
42.39
NACRES:
NA.22
PubChem Substance ID:
24884921
UNSPSC Code:
12352302
MDL number:
MFCD00011078

Key Documents

View All Documentation
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

Product Name

Lithium chloride solution, 0.5 M in anhydrous tetrahydrofuran

InChI

1S/ClH.Li/h1H;/q;+1/p-1

SMILES string

[Li+].[Cl-]

InChI key

KWGKDLIKAYFUFQ-UHFFFAOYSA-M

concentration

0.5 M in anhydrous tetrahydrofuran

impurities

≤50 ppm water

density

0.913 g/mL at 25 °C

Looking for similar products? Visit Product Comparison Guide

Application

Lithium chloride (LiCl) is a source of nucleophilic chloride anion and it can convert alcohols to alkyl chlorides. It catalyzes the ortholithiations of a range of arenes mediated by lithium diisopropylamide (LDA). LiCl solution is also used in the preparation of organozinc halides.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

target_organs

Central nervous system, Respiratory system

supp_hazards

EUH019

Storage Class

3 - Flammable liquids

wgk

WGK 1

flash_point_f

-4.0 °F - closed cup

flash_point_c

-20 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品
This item has

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
MKCN3796
SHBL7230
SHBK0127
SHBJ9471
SHBJ3648

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

On-demand synthesis of organozinc halides under continuous flow conditions.
Berton, Mateo et al.
Nature Protocols, 13(1), 324-324 (2018)
Lithium Chloride.
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
Lekha Gupta et al.
The Journal of organic chemistry, 74(5), 2231-2233 (2009-02-05)
Ortholithiations of a range of arenes mediated by lithium diisopropylamide (LDA) in THF at -78 degrees C reveal substantial accelerations by as little as 0.5 mol % of LiCl (relative to LDA). Substrate dependencies suggest a specific range of reactivity
Sima Rahman et al.
PloS one, 7(12), e51746-e51746 (2012-12-29)
Lineage allocation of the marrow mesenchymal stem cells (MSCs) to osteoblasts and adipocytes is dependent on both Wnt signaling and PPARγ2 activity. Activation of PPARγ2, an essential regulator of energy metabolism and insulin sensitivity, stimulates adipocyte and suppresses osteoblast differentiation
Qi Wu et al.
Proceedings of the National Academy of Sciences of the United States of America, 110(36), 14765-14770 (2013-08-22)
Diphtheria toxin-mediated, acute ablation of hypothalamic neurons expressing agouti-related protein (AgRP) in adult mice leads to anorexia and starvation within 7 d that is caused by hyperactivity of neurons within the parabrachial nucleus (PBN). Because NMDA glutamate receptors are involved
View All Related Papers

Articles

PEPPSI™ Catalysts Overview

PEPPSI™ palladium N-heterocyclic-carbene catalyst system enhances efficiency and functional group tolerance in catalysis.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service