All Photos(1)
About This Item
Empirical Formula (Hill Notation):
C3H7BF3K
Molecular Weight:
149.99
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22
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![[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)](/deepweb/assets/sigmaaldrich/product/structures/130/734/8846aa26-1858-458a-998d-8c306c13bf0f/640/8846aa26-1858-458a-998d-8c306c13bf0f.png)
![[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane](/deepweb/assets/sigmaaldrich/product/structures/825/986/4317978b-1256-4c82-ab74-6a6a3ef948b1/640/4317978b-1256-4c82-ab74-6a6a3ef948b1.png)
Assay
97%
form
solid
mp
>300 °C
SMILES string
[K+].CC(C)[B-](F)(F)F
InChI
1S/C3H7BF3.K/c1-3(2)4(5,6)7;/h3H,1-2H3;/q-1;+1
InChI key
CATSGFLKVWWQST-UHFFFAOYSA-N
Application
Potassium isopropyltrifluoroborate is an organotrifluoroborate that can be used as a reagent:
It can also be employed as a nucleophilic partner in the Suzuki-Miyaura cross-coupling reaction in the presence of a palladium catalyst.
- In the photoelectrochemical C-H alkylation reaction using transition-metal photocatalysts.
- To prepare 2-isopropyl-4-methylquinoline by reacting with 4-methylquinoline (lepidine) in the presence of a photocatalyst.
It can also be employed as a nucleophilic partner in the Suzuki-Miyaura cross-coupling reaction in the presence of a palladium catalyst.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Find documentation for the products that you have recently purchased in the Document Library.
Suzuki-Miyuara cross-coupling reactions and methods developmentusing organotrifluoroborates
Sandrock DL
Angewandte Chemie (International ed. in English), 131(14), 4640-4643 (2010)
Photoelectrochemical C- H alkylation of heteroarenes with organotrifluoroborates
Yan H, et al.
Angewandte Chemie (International ed. in English), 131(14), 4640-4643 (2019)
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