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664979

Sigma-Aldrich

Dichlorobis(2-(diphenylphosphino)ethylamine)ruthenium(II)

95%

Synonym(s):

Dichlorobis[2-(diphenylphosphino-κP)ethanamine-κN]ruthenium

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About This Item

Empirical Formula (Hill Notation):
C28H32Cl2N2P2Ru
CAS Number:
Molecular Weight:
630.49
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.22

Assay

95%

form

solid

reaction suitability

core: ruthenium
reagent type: catalyst

mp

130-135 °C

SMILES string

Cl[Ru]Cl.NCCP(c1ccccc1)c2ccccc2.NCCP(c3ccccc3)c4ccccc4

InChI

1S/2C14H16NP.2ClH.Ru/c2*15-11-12-16(13-7-3-1-4-8-13)14-9-5-2-6-10-14;;;/h2*1-10H,11-12,15H2;2*1H;/q;;;;+2/p-2

InChI key

BJNVYFXBTNBKRU-UHFFFAOYSA-L

Application

Catalyst for:
  • Synthesis of long chain linear fatty acid esters
  • Preparation of ruthenium borohydride complexes for use in hydrogenation reactions
  • Dehydrogenation of ammonia boranes
  • Chemoselective reduction of carboxylic esters
  • Synthesis of ruthenium beta-aminophosphine hydrido/chloro complexes with catalytic activities

Legal Information

Sold under license from Kanata Chemical Technologies Inc. for research purposes only.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Aminophosphine Ligands

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