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663727

2,2,2-Trichloroethoxysulfonamide

Name: 2,2,2-Trichloroethoxysulfonamide
Brand: ALDRICH

97%

Synonym(s):

2,2,2-Trichloroethyl sulfamate, Sulfamic acid, 2,2,2-trichloroethyl ester

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About This Item

Empirical Formula (Hill Notation):

C₂H₄Cl₃NO₃S

CAS Number:

69226-51-3

Molecular Weight:

228.48

MDL number:

MFCD01683146

UNSPSC Code:

12352100

PubChem Substance ID:

24884653

NACRES:

NA.22

Assay

97%

form

solid

mp

52-58 °C

SMILES string

NS(=O)(=O)OCC(Cl)(Cl)Cl

InChI

1S/C2H4Cl3NO3S/c3-2(4,5)1-9-10(6,7)8/h1H2,(H2,6,7,8)

InChI key

VOKONKGVTXWZJI-UHFFFAOYSA-N

Gene Information

human ... STS(412)

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Application

Rh2(esp)2: An Exceptionally Efficient and Selective Catalyst for C-H Amination

Nitrogen source in an intermolecular rhodium-catalyzed (662623) amination of C-H bonds.

WGK

WGK 2

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Catalytic intermolecular amination of C-H bonds: method development and mechanistic insights.

Kristin Williams Fiori et al.

Journal of the American Chemical Society, 129(3), 562-568 (2007-01-18)

Reaction methodology for intermolecular C-H amination of benzylic and 3 degrees C-H bonds is described. This process uses the starting alkane as the limiting reagent, gives optically pure tetrasubstituted amines through stereospecific insertion into enantiomeric 3 degrees centers, displays high

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Rh2(esp)2 Catalyst

New! Rh2(esp)2, and exceptionally efficient and selective catalyst for C-H amination.

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