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Merck
CN

662429

Lumidot CdS

380, core-type quantum dots, 5 mg/mL in toluene

Synonym(s):

Cadmium monosulfide, Cadmium sulfide yellow

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About This Item

Linear Formula:
CdS
CAS Number:
Molecular Weight:
144.48
PubChem Substance ID:
UNSPSC Code:
26111700
MDL number:
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InChI

1S/Cd.S

InChI key

CJOBVZJTOIVNNF-UHFFFAOYSA-N

form

dispersion

concentration

5 mg/mL in toluene

particle size

1.6-1.8 nm

density

0.865 g/mL at 25 °C

λmax

350-370 nm

fluorescence

λem 370-390 nm FWHM 20 nm~

storage temp.

2-8°C

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General description

Organically stabilized cadmium sulfide quantum dots in toluene

Analysis Note

Particle size was determined by TEM according to the procedure in Yu, W. W., et al., Chem. Mater., 2003, 15, 2854.
Quantum yield was measured following the procedure of Qu, L., Peng, X., J. Am. Chem. Soc., 2002, 124-2049.

Other Notes

Lifetime one year if stored properly

Legal Information

Product of Nanoco Technologies sold under US and worldwide patents and patents pending.
Lumidot is a trademark of Sigma-Aldrich Co. LLC

signalword

Danger

Hazard Classifications

Aquatic Chronic 3 - Asp. Tox. 1 - Carc. 1B - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3

target_organs

Central nervous system

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

39.2 °F

flash_point_c

4 °C

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

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Mark P Hendricks et al.
ACS nano, 6(11), 10054-10062 (2012-10-10)
We describe the synthesis of cadmium bis(diphenyldithiophosphinate) (Cd(S(2)PPh(2))(2)) from secondary phosphine sulfides and its conversion to cadmium sulfide nanocrystals. Heating Cd(S(2)PPh(2))(2) and cadmium tetradecanoate (≥4 equiv) to 240 °C results in complete conversion of Cd(S(2)PPh(2))(2) to cadmium sulfide nanocrystals with
Jianjun Tian et al.
Nanoscale, 5(3), 936-943 (2012-11-21)
Photoelectrode made of nanocable structure of ZnO nanorods (NR) coated with TiO(2) nanosheets (NSs) was investigated for CdS/CdSe quantum dot co-sensitized solar cells. ZnO NRs prepared solution reaction at 60 °C served as the backbone for direct electron transport in
Huan-Wei Tseng et al.
Journal of the American Chemical Society, 135(9), 3383-3386 (2013-02-15)
We describe the charge transfer interactions between photoexcited CdS nanorods and mononuclear water oxidation catalysts derived from the [Ru(bpy)(tpy)Cl](+) parent structure. Upon excitation, hole transfer from CdS oxidizes the catalyst (Ru(2+) → Ru(3+)) on a 100 ps to 1 ns
Jianzhong Jiang et al.
Chemical communications (Cambridge, England), 49(19), 1912-1914 (2012-12-14)
A facile method for synthesis of CdS nanoparticles has been described. Monodisperse face-centered cubic CdS NPs could be synthesized in switchable surfactant reverse micelles. The micelles could be broken easily and CdS NPs without a coating of surfactants could be
Luca Ceseracciu et al.
Nanoscale, 5(2), 681-686 (2012-12-12)
The novelty and potential of self-assembled superstructures reside not only in the more commonly investigated optical, magnetic and charge transport properties, but also in their mechanical behaviour, which is strictly dependent on their structural morphology. We report here nanocompression tests

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