661023
Hydroxy(cyclooctadiene)rhodium(I) dimer
95%
Synonym(s):
(Cyclooctadiene)rhodium hydroxide dimer, 1,5-Cyclooctadiene)hydroxyrhodium dimer, Bis(cyclooctadiene)dihydroxodirhodium, Bis[(1,2,5,6-η)-1,5-cyclooctadiene]di--μ-hydroxydirhodium, Bis[(1,5-cyclooctadiene)(hydroxy)rhodium], [Rh(OH)(1,5-cod)]2
About This Item
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![Hydroxy[-(S)-BINAP]-rhodium(I) Dimer 90%](/deepweb/assets/sigmaaldrich/product/structures/349/123/04b0f913-db8b-4c74-96bc-4bb19f629d07/640/04b0f913-db8b-4c74-96bc-4bb19f629d07.png)
Quality Level
Assay
95%
form
solid
reaction suitability
core: rhodium
reagent type: catalyst
greener alternative product characteristics
Catalysis
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mp
199 °C (dec.)
greener alternative category
SMILES string
O[Rh].O[Rh].C1CC=CCCC=C1.C2CC=CCCC=C2
InChI
1S/2C8H12.2H2O.2Rh/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1-2,7-8H,3-6H2;2*1H2;;/q;;;;2*+1/p-2/b2*2-1-,8-7-;;;;
1 of 4
This Item | PFS23 | PFS21 | PFS22 |
|---|---|---|---|
| product line SpheriCal™ | product line SpheriCal™ | product line SpheriCal™ | product line SpheriCal™ |
| application(s) cleaning products | application(s) cleaning products | application(s) cleaning products | application(s) cleaning products |
| form solid | form solid | form solid | form solid |
| shelf life expiry date on the label | shelf life expiry date on the label | shelf life expiry date on the label | shelf life expiry date on the label |
| mol wt Mr 500-1600 Da (Na+-adduct) | mol wt Mr 7500-15000 Da (Na & adduct) | mol wt Mr 1600-3500 Da (Na & adduct) | mol wt Mr 3500-7500 Da (Na+-adduct) |
General description
Application
Rhodium-Catalyzed Oxygenative Addition to Terminal Alkynes for the Synthesis of Esters, Amides, and Carboxylic Acids
Legal Information
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
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Articles
Discover the role of boronic acids in enantioenriched C(sp2)–C(sp2) product synthesis, specifically the rhodium-catalyzed Suzuki–Miyaura-type arylations of allylic halides and cyclobutenes.
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