65133
Methyl 5-methoxy-3-oxovalerate
technical, ≥85% (GC)
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Synonym(s):
Methyl 5-methoxy-3-oxopentanoate, Nazarov reagent
Linear Formula:
CH3O(CH2)2COCH2COOCH3
CAS Number:
Molecular Weight:
160.17
Beilstein:
2042099
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
grade
technical
Assay
≥85% (GC)
form
liquid
refractive index
n20/D 1.44
bp
56-57 °C/0.1 mmHg (lit.)
density
1.10 g/mL at 20 °C (lit.)
SMILES string
COCCC(=O)CC(=O)OC
InChI
1S/C7H12O4/c1-10-4-3-6(8)5-7(9)11-2/h3-5H2,1-2H3
InChI key
OPURNNHYTATPKM-UHFFFAOYSA-N
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Other Notes
Precursor of the unstable methyl 3-oxo-4-pentenoate obtained by acid catalysis (e.g. TosOH) used for annulation reactions. It can be prepared in-situ, review
WGK
WGK 3
Flash Point(F)
closed cup
Flash Point(C)
closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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K.L. Habermas et al.
Org. React., 45, 1-1 (1994)
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