650838
(S)-(+)-1-Benzyloxy-2-propanol
97%
Synonym(s):
(S)-1-O-Benzylpropylene glycol
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About This Item
Empirical Formula (Hill Notation):
C10H14O2
CAS Number:
Molecular Weight:
166.22
MDL number:
UNSPSC Code:
12352112
PubChem Substance ID:
NACRES:
NA.22
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Assay
97%
optical activity
[α]20/D +14.5°, c = 1 in chloroform
refractive index
n20/D 1.510 (lit.)
density
1.044 g/mL at 25 °C (lit.)
SMILES string
C[C@H](O)COCc1ccccc1
InChI
1S/C10H14O2/c1-9(11)7-12-8-10-5-3-2-4-6-10/h2-6,9,11H,7-8H2,1H3/t9-/m0/s1
InChI key
KJBPYIUAQLPHJG-VIFPVBQESA-N
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General description
(S)-(+)-1-Benzyloxy-2-propanol can be used as an effective antiwear agent in aviation turbine fuels, diesel fuels, and light mineral oil.
Application
(S)-(+)-1-Benzyloxy-2-propanol can be used as a reactant to prepare:
- (S)-N-(2-phosphonomethoxypropyl) derivatives of purine and pyrimidine bases (PMP derivatives).
- (S)-1-(benzyloxy)propan-2-yl 4-methylbenzenesulfonate by reacting with tosyl chloride in pyridine.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
10 - Combustible liquids
WGK
WGK 2
Flash Point(F)
227.8 °F
Flash Point(C)
108.8 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Copper-catalyzed cross-coupling of nonactivated secondary alkyl halides and tosylates with secondary alkyl Grignard reagents
Yang C-T, et al.
Journal of the American Chemical Society, 134(27), 11124-11127 (2012)
Enantiomeric impurities in chiral catalysts, auxiliaries, and synthons used in enantioselective syntheses. Part 4
Qiu H, et al.
Tetrahedron Asymmetry, 24(18), 1134-1141 (2013)
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