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650412

Sigma-Aldrich

Borane tetrahydrofuran complex solution

1.0 M in THF, contains 0.005 M N-Isopropyl-N-methyl-tert-butylamine as stabilizer

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Synonym(s):
Borane-THF (1:1), Borane-THF complex (1:1)
Linear Formula:
BH3OC4H8
CAS Number:
14044-65-6
Molecular Weight:
85.94
Beilstein:
3668402
MDL number:
MFCD00012429
UNSPSC Code:
12352005
PubChem Substance ID:
24883750

contains

0.005 M N-Isopropyl-N-methyl-tert-butylamine as stabilizer

Quality Level

200

reaction suitability

reagent type: reductant

concentration

1.0 M in THF

density

0.880 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

B.C1CCOC1

InChI

1S/C4H8O.BH3/c1-2-4-5-3-1;/h1-4H2;1H3

InChI key

RMCYTHFAWCWRFA-UHFFFAOYSA-N

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Application

New, Safer, NIMBA-Stabilized BH3 THF Solutions
This useful reagent for reductions and other transformations is now safer in transport utilizing this new stabilizer
Used to reduce nylon surface amide groups to secondary amines.

Packaging

The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
View returnable container options.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

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Product No.
Description
Pricing

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - STOT SE 3 - Water-react 1

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

EUH019

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Hisanori Ueki et al.
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