637998
Vinylboronic anhydride pyridine complex
95%
Synonym(s):
2,4,6-Trivinylcyclotriboroxane pyridine complex, Trivinyl-boroxin pyridine complex, Trivinylcyclotriboroxane pyridine complex
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About This Item
Empirical Formula (Hill Notation):
C6H9B3O3 · C5H5N
CAS Number:
Molecular Weight:
240.67
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
InChI
1S/C6H9B3O3.C5H5N/c1-4-7-10-8(5-2)12-9(6-3)11-7;1-2-4-6-5-3-1/h4-6H,1-3H2;1-5H
SMILES string
c1ccncc1.C=Cb2ob(C=C)ob(C=C)o2
InChI key
YLHJACXHRQQNQR-UHFFFAOYSA-N
assay
95%
form
solid
storage temp.
−20°C
Quality Level
Related Categories
Application
Reagent used for
Reagent used for Preparation of
- Suzuki-Miyaura cross-coupling
- Stereoselective synthesis via Palladium-catalyzed carboamination
- Alkyl-connected 2-amino-6-vinylpurine (AVP) crosslinking agent to cytosine base in RNA
- Kaiser oxime resin-derived palladacycle as a recoverable polymeric precatalyst in Suzuki-Miyaura cross-coupling reactions in aqueous media
- Kinetic resolution of phosphoryl and sulfonyl esters of binaphthol derivatives via Pd-catalyzed alcoholysis of their vinyl ethers
- Stereoselective isomerization of N-allyl aziridines into Z-enamines by using rhodium hydride catalysis
- Kinetic resolution of axially chiral biaryl derivatives via palladium/chiral diamine ligand-catalyzed alcoholysis
- Transition metal-catalyzed alkenylation of aziridines, cycloaddition and thermal rearrangement reactions
- Intramolecular Heck reaction strategy for synthesis of functionalized tetrahydroanthracenes
Reagent used for Preparation of
- BACE-1 inhibitors and SAR of cyclic sulfone hydroxyethylamines
- Distorted spiropentanes
- Small molecule bradykinin B2 receptor antagonists in angioedema therapy
- Enol Ethers
- Styryl cyclobutanone
signalword
Warning
hcodes
pcodes
Hazard Classifications
Eye Irrit. 2
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
176.0 °F - closed cup
flash_point_c
80 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Intramolecular Heck reaction strategy for the synthesis of functionalized tetrahydroanthracenes: a facile formal total synthesis of the linear abietane diterpene, umbrosone
Sengupta, S.; et al.
Tetrahedron Letters, 46, 1515-1519 (2005)
Amanda F Ward et al.
Organic letters, 13(17), 4728-4731 (2011-08-05)
The stereoselective synthesis of 2,4- and 2,5-disubstituted 1,3-oxazolidines is accomplished via Pd-catalyzed carboamination of O-vinyl-1,2-amino alcohol derivatives. The transformations generate cis-disubstituted products with good to excellent diastereoselectivity, and enantiomerically enriched substrates are converted without loss of optical purity. In addition
Kuan-Jen Su et al.
The Journal of organic chemistry, 75(21), 7494-7497 (2010-10-14)
Tetravinylbenzene 4 was prepared in nearly quantitative yield from commercially available tetrabromobenzene; the improved, one-step procedure now employs Suzuki-Miyaura cross-coupling conditions. Intermolecular cyclopropanation of 4 with dibromocarbene gave a series of gem-dibromide adducts. Intramolecular cyclopropanation of monoadduct 5, putatively by
Kaiser oxime resin-derived palladacycle: A recoverable polymeric precatalyst in Suzuki-Miyaura reactions in aqueous media
Alacid, E.; Najera, C.
Journal of Organometallic Chemistry, 694, 1658-1665 (2009)
Suzuki-Miyaura cross-coupling: preparation of 2'-vinylacetanilide
Cottineau, B.; Kessler, A.; O'Shea, D. F.
Organic Syntheses, 83 (2006)
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