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631582

Sigma-Aldrich

(R)-(+)-2,2′-Bis(methoxymethoxy)-1,1′-binaphthalene

97%

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Linear Formula:
(CH3OCH2OC10H6)2
CAS Number:
Molecular Weight:
374.43
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22

Assay

97%

form

solid

optical activity

[α]20/D +92°, c = 1% in chloroform

mp

101-105 °C (lit.)

SMILES string

COCOc1ccc2ccccc2c1-c3c(OCOC)ccc4ccccc34

InChI

1S/C24H22O4/c1-25-15-27-21-13-11-17-7-3-5-9-19(17)23(21)24-20-10-6-4-8-18(20)12-14-22(24)28-16-26-2/h3-14H,15-16H2,1-2H3

InChI key

YIAQRNNJNMLGTP-UHFFFAOYSA-N

Application

3- or 3,3′-di-substituted products can be obtained easily via ortho-metallation and subsequent treatment with an electrophile to give the corresponding BINOL derivatives.

Pictograms

CorrosionEnvironment

Signal Word

Danger

Hazard Statements

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Cox, P. J. et al
Tetrahedron Letters, 33, 2253-2253 (1992)

Articles

We present an article concerning BINOL and Derivatives.

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