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Key Documents

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631507

Sigma-Aldrich

1,10-Phenanthrolin-5-amine

97%

Synonym(s):

(1,10)-Phenanthrolin-5-ylamine

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About This Item

Empirical Formula (Hill Notation):
C12H9N3
CAS Number:
54258-41-2
Molecular Weight:
195.22
MDL number:
MFCD00455733
UNSPSC Code:
12352100
PubChem Substance ID:
24882426
NACRES:
NA.22
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Quality Level

200

Assay

97%

mp

254-258 °C (lit.)

SMILES string

Nc1cc2cccnc2c3ncccc13

InChI

1S/C12H9N3/c13-10-7-8-3-1-5-14-11(8)12-9(10)4-2-6-15-12/h1-7H,13H2

InChI key

DKPSSMOJHLISJI-UHFFFAOYSA-N

Related Categories

Application

1,10-Phenanthrolin-5-amine can be used in the synthesis of bis-[1,10]phenanthrolin-5-yl-pyromellitic diimide (Bphen-PMD), which can find applications in organic light-emitting devices.[1]

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H302,H317,H318

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Sens. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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    Certificates of Analysis (COA)

    Lot/Batch Number
    MKCT9838
    MKCT2026
    MKCR3309
    MKCP5738
    MKCJ3957

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    Siew San Tan et al.
    Physical chemistry chemical physics : PCCP, 19(37), 25734-25745 (2017-09-16)
    An absorbance-based sensor employing ruthenium bipyridyl with a phenanthroline-fused benzoylthiourea moiety formulated as [Ru(ii)(bpy)
    "Phenanthroline diimide as an organic electron-injecting material for organic light-emitting devices"
    Lee H, et al.
    Royal Society of Chemistry Advances, 2(23), 8762- 8767 (2012)
    Barbara Feist et al.
    Mikrochimica acta, 186(2), 91-91 (2019-01-12)
    Graphene oxide (GO) was chemically functionalized with 5-amino-1,10-phenanthroline. The resulting conjugate (phen-GO) was characterized by scanning electron microscopy and X-ray photoelectron spectroscopy. The experiments show that phen-GO has a high affinity for extraction of Pb(II) ions. Isotherms and kinetics fit
    Mona Amiri et al.
    Dalton transactions (Cambridge, England : 2003), 49(29), 10173-10184 (2020-07-16)
    1,10-Phenanthroline (phen) was grafted to either indium tin oxide (ITO), fluorine-doped tin oxide (FTO), or titanium dioxide (TiO2) semiconductors (SC's) by electrochemical reduction of 5-diazo-phen. The phen ligand is bonded to the semiconductor at C5, and it can be handled
    Kollur Shiva Prasad et al.
    Molecules (Basel, Switzerland), 25(12) (2020-06-26)
    Herein we report the synthesis and structural elucidation of two novel imine-based ligands, 2-(1,10-phenanthrolin-5-yl)imino)methyl)-5-bromophenol (PIB) and N-(1,10-phenanthrolin-5-yl)-1-(thiophen-3-yl)methanimine (PTM) ligands. An in vitro cytotoxicity assay of the synthesized molecules was carried out against breast, cervical, colorectal, and prostate cancer cell lines

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