Skip to Content
Merck
CN

61626

Boron trifluoride methanol complex solution

12.5-15.5% BF3 basis

Synonym(s):

BF3MeOH, Boron fluoride methanol, Boron trifluoride methanol, Boron trifluoride-methanol Complex

Sign In to View Organizational & Contract Pricing.

Select a Size

About This Item

Linear Formula:
BF3 · MeOH
CAS Number:
373-57-9
Molecular Weight:
131.89
UNSPSC Code:
12352104
NACRES:
NA.22
PubChem Substance ID:
57651782
MDL number:
MFCD00071635
Beilstein/REAXYS Number:
3693581

Key Documents

View All Documentation
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

Product Name

Boron trifluoride methanol complex solution, 12.5-15.5% BF3 basis

InChI

1S/CH4O.BF3/c1-2;2-1(3)4/h2H,1H3;

SMILES string

CO.FB(F)F

InChI key

JBXYCUKPDAAYAS-UHFFFAOYSA-N

reaction suitability

core: boron
reagent type: Lewis acid
reagent type: catalyst

concentration

12.5-15.5% boron trifluoride

density

0.859 g/mL at 25 °C

functional group

hydroxyl

Quality Level

100

Related Categories

Application

Boron trifluoride-methanol complex solution can be used for the deprotection of acetylated amines of cyanine dyes to form products with free amino groups. It may be used for the conversion of sulfur-containing phosphoramidates to the corresponding phosphate methyl ester.

General description

BF3-MeOH solution is a Lewis acid-base complex used as a versatile reagent and catalyst in organic synthesis.

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT RE 2 Inhalation - STOT SE 1

target_organs

Eyes,Central nervous system, Kidney

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

60.8 °F - closed cup

flash_point_c

16 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品
This item has

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
SHBT3424
SHBT2188
SHBS9038
SHBS6796
SHBQ9118

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Boron trifluoride?methanol complex?mild and powerful reagent for deprotection of labile acetylated amines.
Miltsov S
Tetrahedron Letters, 44(11), 2301-2303 (2003)
Methanolysis of phosphoramidates with boron trifluoride-methanol complex.
Ryu S
The Journal of Organic Chemistry, 56(16), 4999-5002 (1991)
C Hue-Beauvais et al.
Journal of animal science, 93(4), 1641-1655 (2015-05-29)
Alterations to the metabolic endocrine environment during early life are crucial to mammary gland development. Among these environmental parameters, the initial nutritional event after birth is the consumption of milk, which represents the first maternal support provided to mammalian newborns.
Leila Nejadsadeghi et al.
Molecular biology reports, 42(2), 363-372 (2014-10-01)
Plant cells often increase cold tolerance by reprogramming their genes expression which results in adjusted metabolic alternations, a process enhanced under cold acclimation. In present study, we assessed the changes of membrane fatty acid compositions along with physio-biochemical indices like
Shulin Xiang et al.
Journal of pineal research, 59(1), 60-69 (2015-04-11)
Chemotherapeutic resistance, particularly to doxorubicin (Dox), represents a major impediment to successfully treating breast cancer and is linked to elevated tumor metabolism and tumor over-expression and/or activation of various families of receptor- and non-receptor-associated tyrosine kinases. Disruption of circadian time
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service