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Key Documents

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579726

Sigma-Aldrich

Grubbs Catalyst® M102

Umicore, 97%

Synonym(s):

Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium, Bis(tricyclohexylphosphine)benzylidine ruthenium(IV) dichloride, Dichloro(benzylidene)bis(tricyclohexylphosphine)ruthenium(II), Grubbs Catalyst® 1st Generation, Grubbs Catalyst® M1a (C823)

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100 MG
CN¥1,135.65
1 G
CN¥4,552.32

CN¥1,135.65

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100 MG
CN¥1,135.65
1 G
CN¥4,552.32

About This Item

Empirical Formula (Hill Notation):
C43H72Cl2P2Ru
CAS Number:
172222-30-9
Molecular Weight:
822.96
MDL number:
MFCD01074452
UNSPSC Code:
12161600
PubChem Substance ID:
24881009
NACRES:
NA.22

CN¥1,135.65

Please contact Customer Service for Availability
Request a Bulk Order

Quality Level

100

Assay

97%

reaction suitability

core: ruthenium
reagent type: catalyst
reaction type: Ring-Opening Polymerization

mp

153 °C (dec.)

storage temp.

2-8°C

SMILES string

C[Ph].P(C1CCCCC1)(C2CCCCC2)C3CCCCC3.P(C4CCCCC4)(C5CCCCC5)C6CCCCC6.Cl.Cl.[Ru]

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Show Differences

1 of 4

This Item
211230403857202207
三溴化硼 溶液 1.0 M in methylene chloride

211222

三溴化硼 溶液

三溴化硼 溶液 1.0 M in hexanes

211230

三溴化硼 溶液

三溴化硼 溶液 1.0 M in heptane

403857

三溴化硼 溶液

三溴化硼 ReagentPlus®, 99.9%

202207

三溴化硼

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

200

density

1.467 g/mL at 25 °C

density

0.859 g/mL at 25 °C

density

0.869 g/mL at 25 °C

density

2.60 g/mL at 20 °C (lit.)

form

liquid

form

liquid

form

liquid

form

-

concentration

1.0 M in methylene chloride

concentration

1.0 M in hexanes

concentration

1.0 M in heptane

concentration

-

Application

First metathesis catalyst to be widely used in organic synthesis. Useful for acyclic diene metathesis polymerization (ADMET), Ring-Opening Metathesis Polymerization (ROMP) of strained cyclic olefins, ring opening metathesis (ROM), olefin cross metathesis (CM) and ring closing metathesis (RCM) of terminal olefins under a variety of reactions conditions.

Learn more about our metathesis catalysts

Other Notes

Grubbs Catalyst® Technology for Olefin Metathesis by Aldrich

Legal Information

Product of Umicore

Additional information available at http://www.pmc.umicore.com
Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

Pictograms

Flame
GHS02

Signal Word

Warning

Hazard Statements

H228

Hazard Classifications

Flam. Sol. 2

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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    Certificates of Analysis (COA)

    Lot/Batch Number
    MKCX5593
    0000414176
    0000414176
    0000305137
    MKCW6534

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    Find documentation for the products that you have recently purchased in the Document Library.

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    Charvet, R.: Novak, B. M.
    Macromolecules, 34, 7680-7680 (2001)
    Brummer, O.; Ruckert, a.; Blechert, S.
    Chemistry (Weinheim An Der Bergstrasse, Germany), 3, 441-441 (1997)
    Michaut, M.; Parrain, J.-L.; Santelli, M.
    Chemical Communications (Cambridge, England), 2567-2567 (1998)
    Brzezinska, K.; Wolfe, P. S.
    Macromolecular Chemistry and Physics, 197, 2065-2065 (1996)
    Dongwon Lee et al.
    International journal of nanomedicine, 3(4), 471-476 (2008-01-01)
    The overproduction of hydrogen peroxide is implicated in the progress of numerous life-threatening diseases and there is a great need for the development of contrast agents that can detect hydrogen peroxide in vivo. In this communication, we present a new
    View All Related Papers

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    Trost group's protocol yields α-vinylsilanes from terminal acetylenes using [Cp*Ru(MeCN)3]PF6 catalyst and others for hydrosilylation.

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    Grubbs Group – Prof. Product Portal

    Research focuses on ruthenium alkylidene complexes for versatile olefin metatheses catalysis in the Grubbs group.

    Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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