573515
Germanium(II) chloride dioxane complex (1:1)
Synonym(s):
Dioxanedichlorogermylene, Germanium dichloride-dioxane
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About This Item
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form
solid
Quality Level
reaction suitability
reagent type: catalyst
core: germanium
concentration
25.3-35.8% (silver nitrate titration)
SMILES string
Cl[Ge]Cl.C1COCCO1
InChI
1S/C4H8O2.Cl2Ge/c1-2-6-4-3-5-1;1-3-2/h1-4H2;
InChI key
NYMJLNHIEKAQSD-UHFFFAOYSA-N
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General description
Germanium(II) chloride dioxane complex (1:1) is an organometallic compound used as a reductant in organic synthesis, and to prepare other germanium-based nanoparticles and complexes.
Application
Germanium(II) chloride dioxane complex (1:1) can be used as a precursor:
- To synthesize Germanium oxide nanoparticles.
- To prepare a heterocyclic germylene complex that can be used as an atomic layer deposition precursor to fabricate germanium thin films.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Inhalation - Carc. 2 - Skin Corr. 1B
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Reduction Properties Of Germanium Dichloride With Respect To The Redox-Active Monoiminoacenaphtenone Dpp-Mian}
Journal of Structural Chemistry, 64, 288-301 (2023)
Synthesis of N-heterocyclic stannylene (Sn (II)) and germylene (Ge (II)) and a Sn (II) amidinate and their application as precursors for atomic layer deposition
Chemistry of Materials, 26, 3065-3073 (2014)
From rational design of organometallic precursors to optimized synthesis of core/shell Ge/GeO 2 nanoparticles
Dalton Transactions, 44, 7242-7250 (2015)
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