Skip to Content
Merck
CN
All Photos(1)

Key Documents

572179

Sigma-Aldrich

cis-1-Propen-1-ylboronic acid

≥95.0%

Synonym(s):

cis-Propenylboronic acid

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
H3CCH=CHB(OH)2
CAS Number:
Molecular Weight:
85.90
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22

Assay

≥95.0%

composition

trans isomer, ≤10%

mp

65-70 °C (lit.)

storage temp.

−20°C

SMILES string

C\C=C/B(O)O

InChI

1S/C3H7BO2/c1-2-3-4(5)6/h2-3,5-6H,1H3/b3-2-

InChI key

CBMCZKMIOZYAHS-IHWYPQMZSA-N

Application

cis-1-Propen-1-ylboronic acid can be used:
  • As an intermediate in the preparation of furan-2-yl analog of salvinorin A, a psychoactive natural product.
  • To synthesize antibacterial polyoxygenated dibenzofuran derivatives from phloroglucinol.
  • As a substrate in the palladium-catalyzed cis-vinyl arenes synthesis by reacting with various aryl chlorides.

Other Notes

Contains varying amounts of anhydride

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

219.2 °F - closed cup

Flash Point(C)

104.00 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Synthesis and antibacterial activity of new symmetric polyoxygenated dibenzofurans
Oramas-Royo S, et al.
European Journal of Medicinal Chemistry, 141(9), 178-187 (2017)
Palladium-catalyzed cross-coupling of aryl chlorides with alkenylboronic acids with low E/Z isomerization
Thimmaiah M, et al.
Tetrahedron Letters, 49(39), 5605-5607 (2008)
Kimberly M Lovell et al.
Bioorganic & medicinal chemistry, 20(9), 3100-3110 (2012-04-03)
Modification of the furan ring of salvinorin A (1), the main active component of Salvia divinorum, has resulted in novel neoclerodane diterpenes with opioid receptor affinity and activity. Conversion of the furan ring to an aldehyde at the C-12 position
Ioan-Adrian Stoian et al.
Biosensors & bioelectronics, 155, 112098-112098 (2020-02-25)
A highly selective and sensitive molecularly imprinted polymer (MIP)-based electrochemical sensor was fabricated for the determination of azithromycin, a broad-spectrum macrolide antibiotic, from various biological samples (urine, tears, plasma). The reversible boronate ester bond-mediated, thin (~75 nm) MIP-based biomimetic recognition layer

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service