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Sigma-Aldrich

Poly{[2-[2′,5′-bis(2″-ethylhexyloxy)phenyl]-1,4-phenylenevinylene]-co-[2-methoxy-5-(2′-ethylhexyloxy)-1,4-phenylenevinylene]}

Synonym(s):

BEHP-co-MEH-PPV, Poly[(BEHP-PPV)-co-(MEH-PPV)]

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About This Item

MDL number:
UNSPSC Code:
12352103
NACRES:
NA.23

form

solid

mol wt

Mn 18,900 (typical)

composition

BEHP-PPV, ~60 mol %
MEH-PPV, ~40 mol %

solubility

THF: soluble
chloroform: soluble
xylene: soluble

fluorescence

λex 325 nm; λem 545 nm in chloroform

Mw/Mn

4.7 (typical)

General description

Poly{[2-[2′,5′-bis(2″-ethylhexyloxy)phenyl]-1,4-phenylenevinylene]-co-[2-methoxy-5-(2′-ethylhexyloxy)-1,4-phenylenevinylene]} ((BEHP-PPV)-co-(MEH-PPV)) is a poly(phenylenevinylene) derivate that is highly resistant to photo degradation. It has a high solubility in solvents like chloroform, THF and xylene.

Application

((BEHP-PPV)-co-(MEH-PPV)) is a conjugating polymer that can be used as an active layer in the fabrication of a variety of organic semiconducting devices such as light emitting diodes (LEDs), photovoltaic cells, and photonic crystal lasers.
Light emitting polymer.

Features and Benefits

More stable to photooxidation than other substituted PPV derivatives.

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Electrically pumped photonic crystal laser constructed with organic semiconductors
Cai Y, et al.
Laser Physics Letters, 27(3), 035801-035801 (2017)
Influence of PEDOT: PSS layer on the performances of" bulk-heterojunction" photovoltaic cells based on MEH-PPV: PCBM (1: 4) polymeric blends
Iftimie S, et al.
Digest Journal of Nanomaterials and Biostructures, 6(4), 1631-1638 (2011)
Stability of the J-V characteristics of (BEHP-PPV)-co-(MEH-PPV) based light-emitting diodes
Sanchez JC and Estrada M
Microelectronics reliability, 49(12), 1503-1507 (2009)

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