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569917

Sigma-Aldrich

(R)-(+)-5,5′,6,6′,7,7′,8,8′-Octahydro-1,1′-2-naphthol

95%

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Linear Formula:
(C10H10OH)2
CAS Number:
Molecular Weight:
294.39
MDL number:
UNSPSC Code:
12352002
PubChem Substance ID:
NACRES:
NA.22

Assay

95%

form

solid

optical activity

[α]20/D +73°, c = 1 in THF

mp

160-166 °C (lit.)

InChI

1S/C20H22O2/c21-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)22/h9-12,21-22H,1-8H2

InChI key

UTXIFKBYNJRJPH-UHFFFAOYSA-N

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Application

(R)-(+)-5,5′,6,6′,7,7′,8,8′-octahydro-1,1′-2-naphthol can be used:
  • As a starting material for the preparation of octahydro-binaphthyl based organic light-emitting diodes.
  • As a ligand in the 1,4-hydrophosphinylation of methyl cyclohexene-1-carboxylate using diphenylphosphine oxide, applicable in the synthesis of CyPHOX ligands.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Catalytic asymmetric synthesis of a new class of CyPHOX ligands
Cao M, et al.
Tetrahedron, 75(24), 3282-3291 (2019)
Non-doped and doped circularly polarized organic light-emitting diodes with high performances based on chiral octahydro-binaphthyl delayed fluorescent luminophores
Wu Z, et al.
Journal of Material Chemistry C, 7(23), 7045-7052 (2019)

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