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563919

Sigma-Aldrich

Aluminum chloride

anhydrous, powder, 99.999% trace metals basis

Synonym(s):

Aluminium trichloride, Aluminum(III) chloride, Trichloroaluminum

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About This Item

Linear Formula:
AlCl3
CAS Number:
7446-70-0
Molecular Weight:
133.34
EC Number:
231-208-1
MDL number:
MFCD00003422
UNSPSC Code:
12352302
eCl@ss:
38120507
PubChem Substance ID:
24880139
NACRES:
NA.23

grade

anhydrous

Quality Level

100

vapor pressure

1 mmHg ( 100 °C)

Assay

99.999% trace metals basis

form

powder

reaction suitability

reagent type: catalyst
core: aluminum

impurities

≤15.0 ppm Trace Metal Analysis

mp

190 °C (lit.)

SMILES string

Cl[Al](Cl)Cl

InChI

1S/Al.3ClH/h;3*1H/q+3;;;/p-3

InChI key

VSCWAEJMTAWNJL-UHFFFAOYSA-K

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General description

Aluminum chloride is a strong Lewis acid and a major industrial catalyst. It is also used as a dopant/catalyst modifier to fabricate battery materials and solar cells.

Application

Aluminum chloride can be used:
  • To prepare cost-effective ionic liquid electrolyte for high performance aluminum ion battery.
  • To fabricate modified SnO2 triple layered photoanode for dye sensitized solar cells. This leads to suppression of electron recombination and five-fold enhancement of efficiency.
  • As a precursor to synthesize CsPbCl3 perovskite nanocrystals for bright white light-emitting diodes. It improves photoluminescence quantum yield.

Features and Benefits

  • High purity with trace metal analysis (=< 15 ppm) makes suitable for batteries.
  • High water solubility
  • Stable under battery operation conditions

The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resistance properties. Aluminum nitride can be synthesized from the elemnts with AlCl3 added to help facilitate crystallization.

accessory

Product No.
Description
Pricing

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Supplementary Hazards

EUH014,EUH071

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

危险化学品

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Reactions of Diazirines with Aluminum Chloride: Lewis Acid-Mediated Carbene Generation and Friedel- Crafts Reactions
Moss RA, et al.
Journal of the American Chemical Society, 122(40), 9878-9879 (2000)
Reaction of xylenes with tert.-butylchloride in presence of anhydrous aluminium chloride
Ismail M, et al.
The Journal of Physical Chemistry B, 106(47), 12140-12143 (2008)
Aluminium, Gallium, Indium and Thallium
Chemistry of elements, 216-267 (1997)
Low-temperature modification of mesoporous MCM-41 material with sublimated aluminum chloride in vacuum
Xu M, et al.
The Journal of Physical Chemistry B, 106(47), 12140-12143 (2002)
Lewis-acid catalyzed ene reactions
Snider BB
Accounts of Chemical Research, 13(11), 426-432 (1980)
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