562378
Benzylchlorodimethylsilane
97%
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About This Item
Linear Formula:
C6H5CH2Si(CH3)2Cl
CAS Number:
Molecular Weight:
184.74
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352002
MDL number:
Assay:
97%
InChI
1S/C9H13ClSi/c1-11(2,10)8-9-6-4-3-5-7-9/h3-7H,8H2,1-2H3
SMILES string
C[Si](C)(Cl)Cc1ccccc1
InChI key
ABHNFDUSOVXXOA-UHFFFAOYSA-N
assay
97%
refractive index
n20/D 1.511 (lit.)
bp
101-103 °C/18 mmHg (lit.)
density
1.018 g/mL at 25 °C (lit.)
functional group
phenyl
Application
Benzylchlorodimethylsilane can be used to prepare:
- A ferrocene based mesoporous catalyst, applicable in the oxidation of styrene.
- Silylbissulfide named 3-(benzyldimethylsilyl)-1,3-bis(phenylthio)-1-propene.
- Silyl enyne by reacting with 6-hept-1-yne and nBu-Li, for further use in the intramolecular cross-metathesis to yield silicon substituted diene.
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
163.4 °F - closed cup
flash_point_c
73 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Regulatory Information
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Diversity oriented synthesis of conjugate dienes and alkenylcyclopropanes utilizing silyl group-substituted titanium carbene complexes as bimetallic synthetic reagents
Takeda T, et al.
Tetrahedron, 70(35), 5776-5786 (2014)
Syntheses of 2-silicon-substituted 1, 3-dienes
Choudhury PP, et al.
Journal of Organometallic Chemistry, 754, 88-93 (2014)
Ana C Gomes et al.
Dalton transactions (Cambridge, England : 2003), 42(40), 14612-14620 (2013-08-30)
The surface silanol groups in crystal-like mesoporous phenylene-silica have been derivatized with trimethylsilyl, benzyldimethylsilyl and dimethylsilyl(ferrocene) groups by performing a post-synthetic grafting reaction with the corresponding chlorosilane precursors. The success of the grafting procedure was demonstrated by transmission FT-IR spectroscopy
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