562246
4-(2-Tetrahydro-2H-pyranoxy)phenylmagnesium bromide solution
0.5 M in THF
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About This Item
Empirical Formula (Hill Notation):
C11H13BrMgO2
CAS Number:
Molecular Weight:
281.43
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
reaction suitability
reaction type: Grignard Reaction
concentration
0.5 M in THF
bp
65 °C
density
0.961 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
Br[Mg]c1ccc(OC2CCCCO2)cc1
InChI
1S/C11H13O2.BrH.Mg/c1-2-6-10(7-3-1)13-11-8-4-5-9-12-11;;/h2-3,6-7,11H,4-5,8-9H2;1H;/q;;+1/p-1
InChI key
OHPUQUBYKZJOLY-UHFFFAOYSA-M
Application
4-(2-Tetrahydro-2H-pyranoxy)phenylmagnesium bromide can be used:
- In the preparation of C-2 and C-20-diaryl steroidal derivatives.
- As an intermediate in the synthesis of multiblock copolymers having fullerene backbone for possible applications in photovoltaic devices.
Legal Information
Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
Target Organs
Respiratory system
Supplementary Hazards
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
<1.4 °F - closed cup
Flash Point(C)
< -17 °C - closed cup
Regulatory Information
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Find documentation for the products that you have recently purchased in the Document Library.
Design and Diastereoselective Synthesis of C-2, C-20-Diaryl Steroidal Derivatives
Rey J, et al.
European Journal of Organic Chemistry, 2012(20), 3781-3794 (2012)
Synthesis of donor- acceptor multiblock copolymers incorporating fullerene backbone repeat units
Hiorns RC, et al.
Macromolecules, 43(14), 6033-6044 (2010)
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