556378
Polyaniline (emeraldine base)
average Mw ~20,000
Synonym(s):
Emeraldine base polyaniline
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mol wt
average Mw ~20,000
Quality Level
solubility
m-cresol: soluble
DMAC: soluble
DMF: soluble
DMSO: soluble
NMP: soluble
λmax
328 nm
SMILES string
Brc1nn[nH]c1C.Cl
InChI
1S/C3H4BrN3.ClH/c1-2-3(4)6-7-5-2;/h1H3,(H,5,6,7);1H
InChI key
LYCWKZFKTMHXQA-UHFFFAOYSA-N
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General description
Polyaniline (PAni) emeraldine salt can be prepared by protonation of PAni emeraldine base (PAni-EB). PAni-EB forms at pH>7. Its mechanism against corrosive agents has been explained in a study.
Polyaniline (emeraldine base) (PANI-EB) is a conductive polymer that can be chemically synthesized from aniline by oxidative polymerization of ammonium peroxydisulfate in acidic solution. It is widely used in electronics and optoelectronic applications.
Application
PANI-EB is a conjugating polymer that finds applications in organic light emitting diodes (OLEDs), anticorrosive coatings, chemical sensors and solar cells.
Features and Benefits
Undoped form of conducting polymer (non-conductive).
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Polyaniline nanofiber gas sensors: examination of response mechanisms.
Nano Letters, 4(3), 491-496 (2004)
Polyaniline/TiO2 solar cells.
Synthetic Metals, 156(9-10), 721-723 (2006)
Anticorrosion performances of epoxy coatings modified with polyaniline: A comparison between the emeraldine base and salt forms
Progress in Organic Coatings, 65(1), 88-93 (2009)
Emeraldine Base Polyaniline as an Alternative to Poly(3,4-ethylenedioxythiophene) as a Hole-Transporting Layer
Advances in Functional Materials, 11(6), 407-402 (2001)
Polyaniline nanofibers: facile synthesis and chemical sensors
Journal of the American Chemical Society, 125(2), 314-315 (2003)
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