555959
Dichloroborane dioxane complex solution
3 M in methylene chloride
Sign In to View Organizational & Contract Pricing.
Select a Size
About This Item
Linear Formula:
C4H8O2 · BHCl2
CAS Number:
Molecular Weight:
170.83
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
InChI key
RCKKTUSYECYDLY-UHFFFAOYSA-N
SMILES string
Cl[BH-](Cl)[O+]1CCOCC1
InChI
1S/C4H9BCl2O2/c6-5(7)9-3-1-8-2-4-9/h5H,1-4H2
reaction suitability
reagent type: reductant
concentration
3 M in methylene chloride
density
1.321 g/mL at 25 °C
functional group
ether
storage temp.
2-8°C
Quality Level
Related Categories
Application
Can readily substitute for common hydroborating reagents such as BH3 · THF and BMS.
Reactant for:
- Hydroboration reactions
- Preparation of alkenyl- and alkylboronic acids
Legal Information
U.S. Pat. No. 6,008,414
signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Central nervous system
supp_hazards
Storage Class
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
221.0 °F - closed cup
flash_point_c
105 °C - closed cup
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Josyula, K. V. B. et al
Tetrahedron Letters, 44, 7789-7789 (2003)
Kanth, J. V. B.; Brown, H. C.
Organic Letters, 1, 315-315 (1999)
J V Kanth et al.
The Journal of organic chemistry, 66(16), 5359-5365 (2001-08-04)
Several less volatile oxygen-containing Lewis bases, such as tert-butyl methyl ether, dioxane, anisole, ethyl acetate, beta-chloroethyl ether, and monoglyme, were examined as prospective mono- and dichloroborane carriers. Dioxane, ethyl acetate, and beta-chloroethyl ether form relatively stable boron trichloride adducts, but
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service