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Merck
CN

555169

Poly[(m-phenylenevinylene)-co-(2,5-dioctoxy-p-phenylenevinylene)]

light-emitting polymer, predominantly trans

Synonym(s):

Poly(m -phenylenevinylene-co -2,5-dioctoxy-p -phenylenevinylene)

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About This Item

CAS Number:
184431-56-9
UNSPSC Code:
12352103
NACRES:
NA.23
MDL number:
MFCD03458126

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Product Name

Poly[(m-phenylenevinylene)-co-(2,5-dioctoxy-p-phenylenevinylene)], light-emitting polymer, predominantly trans

SMILES string

O(CCCCCCCC)c1c(cc(cc1)OCCCCCCCC)\C=C\c2cc(ccc2)C=C

InChI

1S/C32H46O2/c1-4-7-9-11-13-15-24-33-31-22-23-32(34-25-16-14-12-10-8-5-2)30(27-31)21-20-29-19-17-18-28(6-3)26-29/h6,17-23,26-27H,3-5,7-16,24-25H2,1-2H3/b21-20+

InChI key

HCMZJCRIYYFYPL-QZQOTICOSA-N

solubility

chloroform: soluble 2 wt. %

λmax

402 nm

fluorescence

λex 405 nm; λem 452 nm in chloroform

Quality Level

100

Related Categories

Application

PmPV in combination with carbon nanotubes (CNTs), graphene and fullerene forms stable nanocomposites with enhanced electrical and mechanical properties. These composites can potentially be used as semiconducting materials for a variety of electronic applications.
Used in the purification of carbon nanotubes.

General description

Poly[(m-phenylenevinylene)-co-(2,5-dioctoxy-p-phenylenevinylene)](PmPV) is a conjugated luminescent polymer with meta linked phenylene ring within the backbone. It has a good non-linear optical response and a high degree of crystallinity.
Semi-conjugated, light-emitting polymer.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Certificates of Analysis (COA)

Lot/Batch Number
MKCP8095
MKBJ2742V
MKBG7612V
MKBF7641V
59796TJ

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Direct Observation of the Ordering and Molecular Folding of Poly [(m-phenylenevinylene)-co-(2, 5-dioctoxy-p-phenylenevinylene)]
Lei SB, et al.
Advanced Materials, 16(9-10), 828-831 (2004)
A composite from poly (m-phenylenevinylene-co-2, 5-dioctoxy-p-phenylenevinylene) and carbon nanotubes: A novel material for molecular optoelectronics
Curran SA, et al.
Advanced Materials, 10(14), 1091-1093 (1998)
Amphiphilic poly (p-phenylene)-driven multiscale assembly of fullerenes to nanowhiskers
Nurmawati MH, et al.
ACS Nano, 2(7), 1429-1436 (2008)
ZUSCHRIFTEN-Preparation and Properties of Polymer-Wrapped Single-Walled Carbon Nanotubes
Star A, et al.
Angewandte Chemie (International Edition in English), 113(9), 1771-1774 (2001)
Effective stimulated emission and excited-state absorption cross-section spectra of poly (m-phenylenevinylene-co-2, 5-dioctoxy-p-phenylenevinylene) and t, t?-didecycloxy-II-distyrylbenzene
Holzer W, et al.
Chemical Physics, 224(2-3), 315-326 (1997)
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