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Merck
CN

554065

Ethyl α-bromophenylacetate

97%

Synonym(s):

α-Bromobenzeneacetic acid ethyl ester, α-Bromophenylacetic acid ethyl ester, 2-Bromo-2-phenylacetic acid ethyl ester, Ethyl (±)-α-bromobenzeneacetate, Ethyl 2-bromo-2-phenylacetate, Ethyl 2-bromophenylacetate

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About This Item

Linear Formula:
C6H5CHBrCOOCH2CH3
CAS Number:
2882-19-1
Molecular Weight:
243.10
NACRES:
NA.22
PubChem Substance ID:
24879372
UNSPSC Code:
12352100
EC Number:
220-735-2
MDL number:
MFCD00013536

Key Documents

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Product Name

Ethyl α-bromophenylacetate, 97%

InChI key

BKTKLDMYHTUESO-UHFFFAOYSA-N

InChI

1S/C10H11BrO2/c1-2-13-10(12)9(11)8-6-4-3-5-7-8/h3-7,9H,2H2,1H3

SMILES string

CCOC(=O)C(Br)c1ccccc1

assay

97%

refractive index

n20/D >1.5390 (lit.)

bp

89-92 °C/0.9 mmHg (lit.)

density

1.389 g/mL at 25 °C (lit.)

functional group

bromo
ester
phenyl

Quality Level

100

Related Categories

Application

Ethyl α-bromophenylacetate (EBPA) may be used to synthesize α-ethoxycarbonyl-N,α-diphenylnitrone.
EBPA may be used as an initiator for the following:
  • polymerization of dimethyl(methacryloyloxymethyl) phosphonate
  • polymerization of methyl methacrylate (MMA)
  • polymerization of trimethylolpropane triacrylate(TMPTA)

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

230.0 °F - closed cup

flash_point_c

110 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
MKCS7719
MKCL5612
MKCG9580
MKBV1507V
MKBP1807V

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Fluorescence self-quenching of substituted N, a-diphenylnitrones in various solvents.
Khoee S and Memarian HR.
Journal of Photochemistry and Photobiology A: Chemistry, 177(2), 276-285 (2006)
Activators regenerated by electron transfer for atom-transfer radical polymerization of (meth)acrylates and related block copolymers.
Wojciech Jakubowski et al.
Angewandte Chemie (International ed. in English), 45(27), 4482-4486 (2006-06-14)
"A dinuclear gold (I) complex as a novel photoredox catalyst for light-induced atom transfer radical polymerization"
Nzulu F, et al.
Polym. Chem., 6(25), 4605-4611 (2015)
Atom transfer radical polymerization of dimethyl (methacryloyloxymethyl) phosphonate.
Mukumoto K, et al.
European Polymer Journal, 56, 11-16 (2014)
Wei Jiang et al.
Journal of colloid and interface science, 521, 62-68 (2018-03-20)
Atom transfer radical polymerization (ATRP) has been considered to be an efficient strategy for constructing functional macromolecules owing to its simple operation and versatile monomers, and thus it is of great significance to develop ideal catalysts with higher activity and
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