Skip to Content
Merck
CN
All Photos(2)

Documents

Safety Information

547816

Sigma-Aldrich

Tris[N,N-bis(trimethylsilyl)amide]europium(III)

98%

Sign Into View Organizational & Contract Pricing
All Photos(2)
Synonym(s):
1,1,1-Trimethyl-N-(trimethylsilyl)silanamine europium salt
Linear Formula:
Eu(N(Si(CH3)3)2)3
CAS Number:
35789-02-7
Molecular Weight:
633.12
MDL number:
MFCD03411248
UNSPSC Code:
12352300
PubChem Substance ID:
24878982
NACRES:
NA.22

Assay

98%

form

solid

reaction suitability

core: europium
reagent type: catalyst

mp

147-154 °C (lit.)

SMILES string

C[Si](C)(C)N([Eu](N([Si](C)(C)C)[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C

InChI

1S/3C6H18NSi2.Eu/c3*1-8(2,3)7-9(4,5)6;/h3*1-6H3;/q3*-1;+3

InChI key

FLADHQMJJLOUHM-UHFFFAOYSA-N

Application

Reactant for:
  • Preferential complexation reactions
  • Pin-wheel shaped heterobimetallis lanthanide alkali metal binaphtholates

Reactant for synthesis of:
  • Isostructural neo-pentoxide derivatives of Group 3 and lanthanide series metals for production of Ln2O3 nanoparticles
  • Anhydrous mononuclear tris(8-quinolinolato)lanthanoid complexes for organic light-emitting devices

Pictograms

FlameCorrosion
GHS02,GHS05

Signal Word

Danger

Hazard Statements

H228,H261,H314

Hazard Classifications

Flam. Sol. 1 - Skin Corr. 1B - Water-react 2

Supplementary Hazards

EUH014

WGK

WGK 3

Flash Point(F)

36.0 °F

Flash Point(C)

2.2 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

新产品

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

A Sebok et al.
Journal of chromatography. A, 1211(1-2), 104-112 (2008-10-14)
This paper presents a derivatization, mass fragmentation study relating to the most common six cholic acids, such as cholic, lithocholic, chenodeoxycholic, ursodeoxycholic, 3-hydroxy,7-ketocholanic and dehydrocholic acids, identified and quantified as pollutants in the aquatic environment at the first time. Derivatizations
Jerry Isaacson et al.
Angewandte Chemie (International ed. in English), 48(10), 1845-1848 (2009-01-29)
(-)-Dysibetaine has been synthesized in 11 steps from readily available L-malic acid (see scheme). The key step is a unique Ugi 4-center-3-component cyclization reaction, where an ester group acts as the carboxylic acid component. The use of 1,1,1,3,3,3-hexamethyldisilazane as an
Natalie M Clark et al.
Chemical communications (Cambridge, England), (39)(39), 5835-5837 (2009-09-30)
'Conventional' (-)-sparteine adducts of lithium and sodium 1,1,1,3,3,3-hexamethyldisilazide (HMDS) were prepared and characterised, along with an unexpected and 'unconventional' hydroxyl-incorporated sodium sodiate, [(-)-sparteine x Na(mu-HMDS)Na x (-)-sparteine](+)[Na(4)(mu-HMDS)(4)(OH)](-)--the complex anion of which is the first inverse crown ether anion.
Nan Li et al.
Lab on a chip, 8(12), 2105-2112 (2008-11-22)
High-density live cell array serves as a valuable tool for the development of high-throughput immunophenotyping systems and cell-based biosensors. In this paper, we have, for the first time, demonstrated a simple fabrication process to form the hexamethyldisilazane (HMDS) and poly(ethylene
Elsa Vennat et al.
Dental materials : official publication of the Academy of Dental Materials, 25(6), 729-735 (2009-01-29)
The objectives of this study were to assess demineralized dentin porosity and quantify the different porous features distribution within the material using mercury intrusion porosimetry (MIP) technique. We compared hexamethyldisilazane (HMDS) drying and lyophilization (LYO) (freeze-drying) in sample preparation. Fifty-six
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service