544396
4-Allyloxybenzaldehyde
97%
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About This Item
Linear Formula:
H2C=CHCH2OC6H4CHO
CAS Number:
Molecular Weight:
162.19
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
255-027-2
MDL number:
InChI key
TYNJQOJWNMZQFZ-UHFFFAOYSA-N
InChI
1S/C10H10O2/c1-2-7-12-10-5-3-9(8-11)4-6-10/h2-6,8H,1,7H2
SMILES string
C=CCOc1ccc(C=O)cc1
assay
97%
refractive index
n20/D 1.568 (lit.)
bp
150-152 °C/18 mmHg (lit.)
density
1.058 g/mL at 25 °C (lit.)
General description
4-Allyloxybenzaldehyde can be prepared by reacting 4-hydroxybenzaldehyde and allylbromide in the presence of a base.4 It can undergo chemoselective dithioacetalization in the presence of cobalt(II)chloride.
Application
4-Allyloxybenzaldehyde may be used in the preparation of:
- 4,6,4′,6′-O-di-4-allyloxybenzylidene-α,α-D-trehalose
- 3-allyl-4-hydroxybenzaldehyde
- (±)-4-allyloxymethamphetamine (ALLMA)
signalword
Warning
hcodes
pcodes
Hazard Classifications
Skin Sens. 1
Storage Class
12 - Non Combustible Liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
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Selective mechanism-based inactivation of rat CYP2D by 4-allyloxymethamphetamine.
Lin LY, et al.
Journal of Pharmacology and Experimental Therapeutics, 277(2), 595-603 (1996)
An isomerization-ring-closing metathesis strategy for the synthesis of substituted benzofurans.
van Otterlo WAL, et al.
Tetrahedron, 61(32), 7746-7755 (2005)
Synthesis and properties of thermoplastic alternating copolymers containing trehalose and siloxane units by hydrosilylation reaction.
Teramoto N, et al.
Polymer Journal, 39(9), 975-975 (2007)
Cobalt (II) chloride catalyzed chemoselective thioacetalization of aldehydes.
De SK.
Tetrahedron Letters, 45(5), 1035-1036 (2004)
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