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About This Item
Empirical Formula (Hill Notation):
C6H7BrN2
CAS Number:
Molecular Weight:
187.04
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Assay
98%
mp
73-76 °C (lit.)
SMILES string
Cc1cnc(N)c(Br)c1
InChI
1S/C6H7BrN2/c1-4-2-5(7)6(8)9-3-4/h2-3H,1H3,(H2,8,9)
InChI key
NDPKXEWDWTZBDG-UHFFFAOYSA-N
Application
2-Amino-3-bromo-5-methylpyridine may be used in the synthesis of:
- 3-bromo-2-chloro-5-methylpyridine
- 3-bromo-2-fluoro-5-methylpyridine
- 8-methyl-1,2,3,5-tetrahydropyrido[3,4-b][1,4]diazepin-4-one
- 3-bromo-2-(ethylamino)-5-methylpyridine
- (3-bromo-5-methylpyridin-2-yl)aniline
- 5-methyl-3-(phenylethynyl)pyridin-2-amine
- 3-[(2-methoxyphenyl)ethynyl]-5-methylpyridin-2-amine
- 3-[(4-methoxyphenyl)ethynyl]-5-methylpyridin-2-amine
- 3-[(3-chlorophenyl)ethynyl]-5-methylpyridin-2-amine
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Synthesis of medium ring nitrogen heterocycles via a tandem copper-catalyzed CN bond formation-Ring-expansion process
Klapars, Artis, et al.
Journal of the American Chemical Society, 126.11, 3529-3533 (2004)
The acid-catalysed synthesis of 7-azaindoles from 3-alkynyl-2-aminopyridines and their antimicrobial activity
Leboho TC, et al.
Organic & Biomolecular Chemistry, 12.2, 307-315 (2014)
Some 2, 5-and 5, 6-Dihalonicotinic acids and their precursors
Setliff FL.
Journal of Chemical and Engineering Data, 15.41, 590-591 (1970)
Phosphonylation of 2-Amino-and 2-Amido-3-bromopyridines and 2-Amino-3-chloroquinoxalines with Triethyl Phosphite
Adam M, et al.
European Journal of Organic Chemistry, 2009.27, 4655-4665 (2009)
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