All Photos(1)
Synonym(s):
6-Fluoro-m-anisaldehyde
Linear Formula:
FC6H3(OCH3)CHO
CAS Number:
Molecular Weight:
154.14
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
Assay
97%
refractive index
n20/D 1.532 (lit.)
bp
229-230 °C (lit.)
density
1.237 g/mL at 25 °C (lit.)
SMILES string
COc1ccc(F)c(C=O)c1
InChI
1S/C8H7FO2/c1-11-7-2-3-8(9)6(4-7)5-10/h2-5H,1H3
InChI key
DKIQXHIAEMGZGO-UHFFFAOYSA-N
General description
2-Fluoro-5-methoxybenzaldehyde can be prepared starting from 2-amino-5-methoxytoluene.
Application
2-Fluoro-5-methoxybenzaldehyde may be used in the synthesis of:
- 5,10,15,20-tetrakis(2-fluoro-5-methoxyphenyl)porphyrin
- aryl(2-fluoro-5-methoxyphenyl)methanones
- 5′-methoxy-4-nitro-2,2′,5-trifluorobenzophenone
- 2-(2-fluoro-5-methoxybenzylidene)-1-(5-bromo-2-morpholinopyrimidin-4-yl) hydrazine
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
WGK
WGK 3
Flash Point(F)
226.4 °F
Flash Point(C)
108 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Yumiko Suzuki et al.
The Journal of organic chemistry, 76(10), 3960-3967 (2011-04-08)
The total synthesis of atroviridin has been accomplished by a linear route involving the N-heterocyclic carbene (NHC)-catalyzed aroylation of the fluorobenzene derivative, Claisen cyclization of the O-propargylated benzophenones, and intramolecular 1,4-addition of the quinone intermediates. The result provides a viable
A new synthesis of benzo [b] thiophenes utilizing an interrupted Pummerer reaction.
Kobayashi K, et al.
Tetrahedron, 65(12), 2430-2435 (2009)
Steric effects on atropisomerism in tetraarylporphyrins.
Crossley MJ, et al.
Journal of the American Chemical Society, 109(2), 341-348 (1987)
Synthesis of new 1, 2, 4-triazole derivatives and their anticorrosion properties on mild steel in hydrochloric acid medium.
Gurudatt DM, et al.
Journal of Molecular Liquids, 211, 275-287 (2015)
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