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Quality Level
Assay
98%
refractive index
n20/D 1.42 (lit.)
density
0.807 g/mL at 25 °C (lit.)
SMILES string
CCCCCCCCCCCCF
InChI
1S/C12H25F/c1-2-3-4-5-6-7-8-9-10-11-12-13/h2-12H2,1H3
InChI key
YHYBNVZCQIDLSQ-UHFFFAOYSA-N
General description
1-Fluorododecane is a long chain 1-fluoroalkane. It can be synthesized from the reaction between 1-dodecanol, N,N-diethyl-α,α-difluoro-[3,5-bis(1H,1H,2H,2H-perfluorodecyl)benzyl]amine and heptane. 1-Fluorododecane undergoes reaction with dibromomethane and titanocene dichloride in the presence of triethyl aluminium (Et3Al) to afford a mixture of 1-chlorododecane and 1-bromododecane. 1-Fluorododecane can also be prepared from 1-hydroxydodecane.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 2 Oral - Aquatic Chronic 4
WGK
WGK 3
Flash Point(F)
223.0 °F
Flash Point(C)
106.1 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Fluorination of alcohols and diols with a novel fluorous deoxy-fluorination reagent.
Journal of Fluorine Chemistry, 130(2), 348-353 (2009)
Regioselective Hydroxylation of C12?C15 Fatty Acids with Fluorinated Substituents by Cytochrome P450 BM3.
Chemistry?A European Journal , 19(41), 13680-13691 (2013)
Halogen Exchange Reaction of Aliphatic Fluorine Compounds with Organic Halides as Halogen Source.
Organic Letters, 17(24), 5942-5945 (2015)
Vapor Pressures and Boiling Points of the 1-Fluoroalkanes, 1-Chloroalkanes, 1-Bromoalkanes, and 1-Iodoalkanes, C1to C20.
Journal of Chemical and Engineering Data, 6(2), 268-270 (1961)
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