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Quality Level
product line
ReagentPlus®
Assay
99%
autoignition temp.
536 °F
manufacturer/tradename
Sigma-Aldrich
refractive index
n20/D 1.419 (lit.)
bp
169-170 °C/70 mmHg (lit.)
mp
−80 °C (lit.)
density
1.076 g/mL at 25 °C (lit.)
SMILES string
COC(=O)CC(C)=O
InChI
1S/C5H8O3/c1-4(6)3-5(7)8-2/h3H2,1-2H3
InChI key
WRQNANDWMGAFTP-UHFFFAOYSA-N
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Related Categories
Application
Methyl acetoacetate (MAA) can be used as a reactant for:
- Transesterification with alcohols by using various catalysts.
- The synthesis of 4-methylcoumarins with phenol in presence of zinc and I2 as catalysts.
- Asymmetric heterogeneous hydrogenation reactions by transition metal catalysts.
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Dam. 1
WGK
WGK 1
Flash Point(F)
158.0 °F
Flash Point(C)
70 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.
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Enantioselective hydrogenation of methyl acetoacetate catalyzed by nickel supported on activated carbon or graphite.
Applied Catalysis A: General, 208(1-2), 91-98 (2001)
Synergism between microwave and enzyme catalysis in intensification of reactions and selectivities: transesterification of methyl acetoacetate with alcohols.
J. Mol. Catal. A: Chem., 223(1-2), 51-56 (2004)
Zinc mediated transesterification of ?-ketoesters and coumarin synthesis.
Tetrahedron Letters, 43(47), 8583-8586 (2002)
Synthesis and studies of 6, 6′ -BINAP derivatives for the heterogeneous asymmetric hydrogenation of methyl acetoacetate.
Tetrahedron Asymmetry, 13(11), 1141-1146 (2002)
Circulation, 130(24), 2136-2142 (2014-11-08)
Mycotic aortic aneurysm (MAA) is a rare and life-threatening disease. The aim of this European multicenter collaboration was to study the durability of endovascular aortic repair (EVAR) of MAA, by assessing late infection-related complications and long-term survival. All EVAR treated
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