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Merck
CN

534102

Methylamine solution

greener alternative

33 wt. % in absolute ethanol ((denatured with 1% toluene))

Synonym(s):

Monomethylamine

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About This Item

Linear Formula:
CH3NH2
CAS Number:
74-89-5
Molecular Weight:
31.06
UNSPSC Code:
12352302
PubChem Substance ID:
24878015
NACRES:
NA.22
Beilstein/REAXYS Number:
741851
MDL number:
MFCD00008104

Key Documents

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Product Name

Methylamine solution, 33 wt. % in absolute ethanol ((denatured with 1% toluene))

InChI

[1S/CH5N/c1-2/h2H2,1H3]
1S/CH5N/c1-2/h2H2,1H3

InChI key

[BAVYZALUXZFZLV-UHFFFAOYSA-N]
BAVYZALUXZFZLV-UHFFFAOYSA-N

SMILES string

CN

greener alternative product characteristics

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concentration

33 wt. % in absolute ethanol ((denatured with 1% toluene))

impurities

≤1.0% water

refractive index

n20/D 1.360-1.372

density

0.756 g/mL at 25 °C

functional group

amine

greener alternative category

, Enabling

storage temp.

2-8°C

Quality Level

200

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Application

Methylamine solution in absolute ethanol can be used as a precursor that facilitates the synthesis of perovskite based materials. It can also be used as a deactivating agent to study the catalytic performance of acidic macroporous ion exchange resins. It can be annealed to reduce impurity in the grain boundaries, improve the stability and efficiency of the perovskite solar cells.

General description

Methylamine solution is a 33wt.% solution of methylamine in absolute ethanol. Methylamine is an aliphatic primary amine. It participates in the synthesis of isothiazolium salts. Chemical degradation of methylamine solution of γ-irradiated poly(ε-caprolactone) has been described. Maillard reaction of D-glucose and methylamine in aqueous acetic acid has been reported.
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Danger

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 1

flash_point_f

-9.0 °F - closed cup

flash_point_c

-22.8 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品
易制爆化学品
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Certificates of Analysis (COA)

Lot/Batch Number
BCCP0958
SHBT2575
SHBT0193
SHBR8751
BCCG6848

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Preparation of the MacMillan imidazolidinones.
Samulis L and Tomkinson NCO.
Tetrahedron, 67(23), 4263-4267 (2011)
Bianca-Maria Bresolin et al.
Nanomaterials (Basel, Switzerland), 10(1) (2020-01-16)
The development of visible-light active photocatalysts is a current challenge especially energy and environmental-related fields. Herein, methylammonium lead iodide perovskite (MAIPb) was chosen as the novel semiconductor material for its ability of absorbing visible-light. An easily reproducible and efficient method
Degradability of radiation crosslinked PCL in the supercooled state under various environments.
Darwis D, et al.
Polymer Degradation and Stability, 65(2), 279-285 (1999)
Selvakumar Pitchaiya et al.
Scientific reports, 10(1), 6835-6835 (2020-04-24)
Perovskite solar cells (PSCs) composed of organic polymer-based hole-transporting materials (HTMs) are considered to be an important strategy in improving the device performance, to compete with conventional solar cells. Yet the use of such expensive and unstable HTMs, together with
Bernard Wenger et al.
Nature communications, 8(1), 590-590 (2017-09-21)
Ultralow trap densities, exceptional optical and electronic properties have been reported for lead halide perovskites single crystals; however, ambiguities in basic properties, such as the band gap, and the electronic defect densities in the bulk and at the surface prevail.
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