529982
2-Iodobiphenyl
96%
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About This Item
Linear Formula:
C6H5C6H4l
CAS Number:
Molecular Weight:
280.10
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
218-303-3
MDL number:
Assay:
96%
InChI key
QFUYDAGNUJWBSM-UHFFFAOYSA-N
InChI
1S/C12H9I/c13-12-9-5-4-8-11(12)10-6-2-1-3-7-10/h1-9H
SMILES string
Ic1ccccc1-c2ccccc2
assay
96%
refractive index
n20/D 1.662 (lit.)
bp
300 °C (lit.)
density
1.59 g/mL at 25 °C (lit.)
functional group
iodo, phenyl
Quality Level
Related Categories
General description
2-Iodobiphenyl is an ortho-halogenated biphenyl that can be synthesized from 2-aminobiphenyl.
Application
2-Iodobiphenyl may be used in the synthesis of dibenziodolium tosylate by reacting with hydroxy(tosyloxy)iodo] benzene in acetonitrile.
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
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[Hydroxy (tosyloxy) iodo] benzene, a versatile reagent for the mild oxidation of aryl iodides at the iodine atom by ligand transfer.
Koser GF and Wettach RH.
The Journal of Organic Chemistry, 45(8), 1542-1543 (1980)
Dicyclic Hydrocarbons. I. 2-Aklylbiphenyls.
Goodman IA and Wise PH.
Journal of the American Chemical Society, 72(7), 3076-3079 (1950)
Michael Barclay et al.
Physical chemistry chemical physics : PCCP, 21(8), 4556-4567 (2019-02-12)
We present a combined theoretical and experimental study on the ionization and primary fragmentation channels of the mono-halogenated biphenyls; 2-chlorobiphenyl, 2-bromobiphenyl and 2-iodobiphenyl. The ionization energies (IEs) of the 2-halobiphenyls and the appearance energies (AEs) of the principal fragments are
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