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Key Documents

Safety Information

528862

Sigma-Aldrich

2-Bromo-4,6-dimethylaniline

97%

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About This Item

Linear Formula:
BrC6H2(CH3)2NH2
CAS Number:
Molecular Weight:
200.08
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:

Assay

97%

mp

43-47 °C (lit.)

functional group

bromo

SMILES string

Cc1cc(C)c(N)c(Br)c1

InChI

1S/C8H10BrN/c1-5-3-6(2)8(10)7(9)4-5/h3-4H,10H2,1-2H3

InChI key

YOSJCQJJIHEUKA-UHFFFAOYSA-N

Application

2-Bromo-4,6-dimethylaniline may be used in the synthesis of 2-phenoxy-4,6-dimethylaniline and (4aR,9aR)-4a,6,8-trimethyl-4,4a,9,9a-tetrahydro-1H-carbazol-2(3H)-one.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

230.0 °F - closed cup

Flash Point(C)

110 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Palladium-catalyzed gamma-arylation of beta,gamma-unsaturated ketones: application to a one-pot synthesis of tricyclic indolines.
Alan M Hyde et al.
Angewandte Chemie (International ed. in English), 47(1), 177-180 (2007-11-23)
Using intelligent/random library screening to design focused libraries for the optimization of homogeneous catalysts: Ullmann ether formation.
Fagan PJ, et al.
Journal of the American Chemical Society, 122(21), 5043-5051 (2000)

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