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Safety Information

526053

Sigma-Aldrich

Diethyl-4-methylbenzylphosphonate

97%

Synonym(s):

Diethyl p-tolylmethylphosphonate, [(4-Methylphenyl)methyl]phosphonic acid diethyl ester

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About This Item

Linear Formula:
CH3C6H4CH2P(O)(OC2H5)2
CAS Number:
Molecular Weight:
242.25
EC Number:
MDL number:
UNSPSC Code:
12352108
PubChem Substance ID:

Assay

97%

reaction suitability

reaction type: C-C Bond Formation

refractive index

n20/D 1.497 (lit.)

bp

110 °C/0.2 mmHg (lit.)

density

1.07 g/mL at 25 °C (lit.)

SMILES string

CCOP(=O)(Cc1ccc(C)cc1)OCC

InChI

1S/C12H19O3P/c1-4-14-16(13,15-5-2)10-12-8-6-11(3)7-9-12/h6-9H,4-5,10H2,1-3H3

InChI key

QKGBKPZAXXBLJE-UHFFFAOYSA-N

Application

Reactant involved in:
  • Synthesis of stilbenes via oxidation and Horner-Emmons reactions
  • Intramolecular cyclization of aryl ethers, amines, and amides
  • Studies of the effects of functional groups on the performance of blue organic LEDs
  • Olefination reactions
  • Preparation of antimalarial agents

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

230.0 °F - closed cup

Flash Point(C)

110 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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