All Photos(1)
Linear Formula:
(C6H5)2NCH3
CAS Number:
Molecular Weight:
183.25
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
Quality Level
Assay
96%
refractive index
n20/D 1.623 (lit.)
bp
293 °C (lit.)
density
1.05 g/mL at 25 °C (lit.)
SMILES string
CN(c1ccccc1)c2ccccc2
InChI
1S/C13H13N/c1-14(12-8-4-2-5-9-12)13-10-6-3-7-11-13/h2-11H,1H3
InChI key
DYFFAVRFJWYYQO-UHFFFAOYSA-N
Related Categories
General description
N-Methyldiphenylamine is an aromatic tertiary amine. It undergoes transformation to N-methylcarbazole (C) via a photochemical reaction.
Application
N-Methyldiphenylamine may be used for the synthesis of phosphonium ion salts. It may also be used as a starting reagent for the preparation of bis(4-carboxyphenyl)-N-methylamine (H2CPMA).
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
WGK
WGK 3
Flash Point(F)
closed cup
Flash Point(C)
closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Frustrated Lewis pair-mediated C?O or C?H bond activation of ethers.
Holthausen MH, et al.
Chemical Communications (Cambridge, England), 50(70), 10038-10040 (2014)
Tae Kyung Kim et al.
Inorganic chemistry, 52(2), 589-595 (2012-12-29)
A luminescent lithium metal-organic framework (MOF) is constructed from the solvothermal reaction of Li(+) and a well-designed organic ligand, bis(4-carboxyphenyl)-N-methylamine (H(2)CPMA). A Li-based MOF can detect an explosive aromatic compound containing nitro groups as an explosophore, by showing a dramatic
Reaction patterns and kinetics of the photoconversion of N-methyldiphenylamine to N-methylcarbazole.
Forster EW, et al.
Journal of the American Chemical Society, 95(10), 3108-3115 (1973)
Natália M Monezi et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 173, 462-467 (2016-10-08)
The distinct thermochromism observed in solutions containing N,N-dimethylaniline (DMA) and N,N-diethylaniline (DEA) and SO2 was investigated by resonance Raman spectroscopy in a wide range of temperatures. The results indicate in addition to the charge transfer (CT) complexes DMA-SO2 and DEA-SO2
Minoru Yamaji et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 14(9), 1673-1684 (2015-07-07)
Photochemical processes of 4-tert-butyl-4'-methoxydibenzoylmethane (Avobenzone, AB), 4-phenylbenzoylbenzoyl-, 4-phenylbenzoyl-2'-furanyl- and 4-phenylbenzoyl-2'-thenoylmethanes (PB@Ph, PB@F and PB@T, respectively) substituted with Br and Cl at the C2 position were studied by stationary and laser flash photolyses in solution. The absorption spectral features showed that
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