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Merck
CN

520721

Iridium(III) chloride

99.8% trace metals basis

Synonym(s):

Iridium trichloride, Trichloroiridium

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About This Item

Linear Formula:
IrCl3
CAS Number:
10025-83-9
Molecular Weight:
298.58
NACRES:
NA.23
PubChem Substance ID:
24874162
UNSPSC Code:
12352302
EC Number:
233-044-6
MDL number:
MFCD00011063
Assay:
99.8% trace metals basis
Form:
powder or crystals
Solubility:
H2O: insoluble(lit.)
aliphatic hydrocarbons: insoluble(lit.)
aqueous acid: insoluble(lit.)

Key Documents

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Product Name

Iridium(III) chloride, 99.8% trace metals basis

InChI key

DANYXEHCMQHDNX-UHFFFAOYSA-K

InChI

1S/3ClH.Ir/h3*1H;/q;;;+3/p-3

SMILES string

Cl[Ir](Cl)Cl

assay

99.8% trace metals basis

form

powder or crystals

reaction suitability

core: iridium

impurities

≤2500.0 ppm Trace Metal Analysis

mp

763 °C (lit.)

solubility

H2O: insoluble(lit.)
aliphatic hydrocarbons: insoluble(lit.)
aqueous acid: insoluble(lit.)

application(s)

PEM fuel cells
homogeneous catalyst
material synthesis precursor

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Application

Iridium(III) chloride can be used:
  • As a precursor to synthesize Iridium nanoparticles.
  • As a starting material synthesize Iridium complexes that can be used to fabricate OLEDs.
  • As a catalyst for the ring opening of epoxidesby aryl, heterocyclic, or aliphatic amines.

General description

Iridium(III) chloride is a crystalline inorganic solid with excellent electrical conductivity and good transmission in the infrared range. It is used in the field of catalysis and nanomaterial synthesis.

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H319

Hazard Classifications

Eye Irrit. 2

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCX7727
MKCX4932
MKCW8039
MKCT3508
MKCS8797

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Ditopic bis-terdentate cyclometallating ligands and their highly luminescent dinuclear iridium (III) complexes
Pierre-Henri Lanoe, et al.
Chemical Communications (Cambridge, England), 50, 6831-6834 (2014)
Aminolysis of epoxides using iridium trichloride as an efficient catalyst
Jyoti Agarwal, et al.},
Synthesis, 2009, 2790-2796 (2009)
Effective hydrogenation of Haloaromatic nitro compounds catalysed by iridium nanoparticles deposited on multiwall carbon nanotubes
Hua-Bin Li, et al.
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 46, 1499-1505 (2016)
Rajendra Prasad Paitandi et al.
European journal of medicinal chemistry, 84, 17-29 (2014-07-12)
Efficacy of the ferrocene appended piano-stool dipyrrinato complexes [(η(6)-C6H6)RuCl(fcdpm)] (1), [(η(6)-C10H14)RuCl(fcdpm)] (2), [(η(6)-C12H18)RuCl(fcdpm)] (3) [(η(5)-C5Me5)RhCl(fcdpm)] (4) and [(η(5)-C5Me5)IrCl(fcdpm)] (5) [fcdpm = 5-ferrocenyldipyrromethene] toward anticancer activity have been described. Binding of the complexes with calf thymus DNA (CT-DNA) and BSA (bovine

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