51974
Nonafluoro-1-butanesulfonyl chloride
≥98.0% ((GC))
Synonym(s):
Perfluoro-1-butanesulfonyl chloride
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About This Item
Empirical Formula (Hill Notation):
C4ClF9O2S
CAS Number:
Molecular Weight:
318.55
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Product Name
Nonafluoro-1-butanesulfonyl chloride, ≥98.0% ((GC))
InChI
1S/C4ClF9O2S/c5-17(15,16)4(13,14)2(8,9)1(6,7)3(10,11)12
SMILES string
FC(F)(F)C(F)(F)C(F)(F)C(F)(F)S(Cl)(=O)=O
InChI key
IRFCLLARAUQTNK-UHFFFAOYSA-N
assay
≥98.0% ((GC))
functional group
fluoro
Quality Level
Other Notes
Reagent for fluoro-tagging of nucleophiles
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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C.W. Lindsley et al.
Tetrahedron Letters, 43, 4225-4225 (2002)
Graphitic carbon nitride polymer as a recyclable photoredox catalyst for fluoroalkylation of arenes.
Moritz Baar et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(2), 526-530 (2014-11-22)
Heterogeneous catalysis for trifluoromethylations and perfluoroalkylations has been performed. Through the usage of cheap, metal-free and recyclable mesoporous graphitic carbon nitride (mpg-CN) it was possible to fluoroalkylate various arenes by the reductive activation of sulfonyl chlorides with visible light. Thus
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