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511579

Sigma-Aldrich

Tetrakis(triphenylphosphine)palladium, polymer-bound

100-200 mesh, extent of labeling: 0.4-0.9 mmol/g loading, 2 % cross-linked with divinylbenzene

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Synonym(s):
Palladium-tetrakis(triphenylphosphine), polymer-bound
MDL number:
MFCD00010012
UNSPSC Code:
12352200
PubChem Substance ID:
24873549
NACRES:
NA.22

form

solid

crosslinking

2 % cross-linked with divinylbenzene

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reaction type: solution phase peptide synthesis
reagent type: catalyst

extent of labeling

0.4-0.9 mmol/g loading

particle size

100-200 mesh

storage temp.

2-8°C

SMILES string

[Pd].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9.c%10ccc(cc%10)P(c%11ccccc%11)c%12ccccc%12

InChI

1S/4C18H15P.Pd/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h4*1-15H;

InChI key

NFHFRUOZVGFOOS-UHFFFAOYSA-N

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Application

Polymer-bound catalyst for Suzuki Coupling reactions.,

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Jang, S-B.
Tetrahedron Letters, 38, 1793-1793 (1997)
Jang, S-B.
Tetrahedron Letters, 38, 4421-4421 (1997)

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