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510068

Sigma-Aldrich

Raney®-Nickel

W.R. Grace and Co. Raney® 3202, slurry, in H2O, active catalyst

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Synonym(s):
Nickel sponge
Linear Formula:
AlNi
CAS Number:
7440-02-0
MDL number:
MFCD00167392
UNSPSC Code:
12352300
PubChem Substance ID:
24873472
NACRES:
NA.22

Quality Level

100

form

slurry

reaction suitability

core: nickel
reagent type: catalyst

manufacturer/tradename

W.R. Grace and Co. Raney® 3202

concentration

in H2O

SMILES string

[Al].[Ni]

InChI

1S/Al.Ni

InChI key

NPXOKRUENSOPAO-UHFFFAOYSA-N

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Application

Useful as a selective reducing agent for hydrogenation of organic compounds

Legal Information

Raney is a registered trademark of W.R. Grace & Co.-Conn.

Signal Word

Danger

Hazard Statements

H250,H317,H351,H372

Hazard Classifications

Carc. 2 - Pyr. Liq. 1 - Skin Sens. 1 - STOT RE 1

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

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Barrero, A. F.; Alvarez-Manzaneda, E. J. et al.
Synthesis, 197-197 (2000)
Tsukinoki, T.; Kanda, T.
Tetrahedron Letters, 41, 5865-5865 (2000)
Nitrile reduction in the presence of Boc-protected amino groups by catalytic hydrogenation over palladium-activated Raney-nickel.
B Klenke et al.
The Journal of organic chemistry, 66(7), 2480-2483 (2001-04-03)
Toth, M.; Somsak, L.,
Tetrahedron Letters, 42, 2723-2723 (2001)
A J Feilzer et al.
Nederlands tijdschrift voor tandheelkunde, 120(6), 335-341 (2013-07-19)
Orally applied metal alloys can cause undesirable physical effects. A distinction needs to be made in this respect between local and systemic reactions and toxic and immunological reactions. A case is presented which illustrates this problem. In this case, the
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Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

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