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510033

Sigma-Aldrich

Raney®-Nickel

W.R. Grace and Co. Raney® 2400, slurry, in H2O, active catalyst

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Synonym(s):
Raney Ni, Nickel sponge
Linear Formula:
AlNi
CAS Number:
7440-02-0
MDL number:
MFCD00167392
UNSPSC Code:
12352300
PubChem Substance ID:
24873469
NACRES:
NA.22

Quality Level

100

form

slurry

reaction suitability

core: nickel
reagent type: catalyst

manufacturer/tradename

W.R. Grace and Co. Raney® 2400

concentration

in H2O

SMILES string

[Al].[Ni]

InChI

1S/Al.Ni

InChI key

NPXOKRUENSOPAO-UHFFFAOYSA-N

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Application

Used as reducing agent for hydrogenation of organic compounds, e.g. hydrogenation of nitriles to amines, reduction of aromatic groups to the corresponding saturated compounds, hydrogenation reaction of β-keto esters, rreduction of amination, and also used as 3-alkylation of oxindole with alcohol, and Ullman-type cross coupling, and dehalogenation reactions.

Legal Information

Raney is a registered trademark of W.R. Grace & Co.-Conn.

Signal Word

Danger

Hazard Statements

H250,H317,H351,H372

Hazard Classifications

Carc. 2 - Pyr. Liq. 1 - Skin Sens. 1 - STOT RE 1

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

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Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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  1. Which document(s) contains shelf-life or expiration date information for a given product?

    If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.

  2. How do I get lot-specific information or a Certificate of Analysis?

    The lot specific COA document can be found by entering the lot number above under the "Documents" section.

  3. How do I find price and availability?

    There are several ways to find pricing and availability for our products. Once you log onto our website, you will find the price and availability displayed on the product detail page. You can contact any of our Customer Sales and Service offices to receive a quote.  USA customers:  1-800-325-3010 or view local office numbers.

  4. What is the Department of Transportation shipping information for this product?

    Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product. 

  5. What is the pH of the Raney® 2400 Nickel, Product 510033?

    The pH of the water layer is expected to be in the range of 8.5-12.5.

  6. What is the composition of the Raney® 2400 Nickel, Product 510033?

    According to the manufacturer, the Raney® 2400 Nickel contains about >81.0% nickel, 6.0-13.0% aluminum, 2.0-3.0% iron, and 2.0-3.0% chromium.

  7. What is the particle size of the Raney® 2400 Nickel, Product 510033, solid that is used in the slurry?

    The particle size is expected to be between 25-55 microns.

  8. What is the bulk density of Raney® 2400 Nickel, Product 510033?

    According to the manufacturer, the bulk density is about 15-17 lbs/gallon.

  9. In what applications can Raney® 2400 Nickel, Product 510033, be used?

    It is typically used as a hydrogenation catalyst for nitrile, olefin and nitro group reductions.

  10. My question is not addressed here, how can I contact Technical Service for assistance?

    Ask a Scientist here.

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