50062
Glycidyl propargyl ether
technical, ≥90% (GC)
Synonym(s):
2,3-Epoxypropyl propargyl ether
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About This Item
Empirical Formula (Hill Notation):
C6H8O2
CAS Number:
Molecular Weight:
112.13
Beilstein:
1098793
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
grade
technical
Assay
≥90% (GC)
refractive index
n20/D 1.448
density
1.040 g/mL at 20 °C (lit.)
SMILES string
C#CCOCC1CO1
InChI
1S/C6H8O2/c1-2-3-7-4-6-5-8-6/h1,6H,3-5H2
InChI key
SYFZCLMMUNCHNH-UHFFFAOYSA-N
Related Categories
General description
Glycidyl propargyl ether (GPE) is a glycidyl ether containing a terminal alkyne group.
Application
Glycidyl propargyl ether may be used in the synthesis of:
- propargyl-functional poly(carbonate)s
- hyperbranched polyglycerol (hbPG)
- alkyne-functionalized polytetrahydrofuran (PTHF) diols
- dextran-based cyclodextrin polymers
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Inhalation - Carc. 1B - Resp. Sens. 1
WGK
WGK 3
Flash Point(F)
156.2 °F - closed cup
Flash Point(C)
69 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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One-step synthesis of multi-alkyne functional hyperbranched polyglycerols by copolymerization of glycidyl propargyl ether and glycidol.
Schull C, et al.
Polym. Chem., 4(17), 4730-4736 (2013)
Combining cationic ring-opening polymerization and click chemistry for the design of functionalized polyurethanes.
Basko M, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 49(7), 1597-1604 (2011)
Zoltán Fülöp et al.
Carbohydrate polymers, 97(2), 635-642 (2013-08-06)
Cyclodextrins and their water-soluble derivatives are excellent solubilizers and stabilizers and widely used as enabling pharmaceutical excipients. However, still new cyclodextrin derivatives are being designed and synthesized in an effort to improve their physicochemical properties. In this study physicochemical and
Propargyl-Functional Aliphatic Polycarbonate Obtained from Carbon Dioxide and Glycidyl Propargyl Ether.
Hilf J and Frey H.
Macromolecular Rapid Communications, 34(17), 1395-1400 (2013)
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