All Photos(1)
Linear Formula:
C6H5CH2CH2ZnBr
CAS Number:
Molecular Weight:
250.45
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
Quality Level
concentration
0.5 M in THF
bp
65 °C
density
0.965 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
Br[Zn]CCc1ccccc1
InChI
1S/C8H9.BrH.Zn/c1-2-8-6-4-3-5-7-8;;/h3-7H,1-2H2;1H;/q;;+1/p-1
InChI key
SEXSOTWHLBYVNF-UHFFFAOYSA-M
Related Categories
Application
Phenethylzinc bromide can be used as a reagent:
- In the transition metal-catalyzed Negishi cross-coupling reaction to prepare aryl or heteroaryl derivatives by reacting with organic halides or triflates via carbon-carbon bond formation.
- To prepare (4-phenyl-1-butyn-1-yl)benzene by reacting with phenylacetylene via palladium-catalyzed cross-coupling reaction.
- To synthesize benzyl substituted thienopyrimidine derivatives.
Legal Information
Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
Target Organs
Central nervous system, Respiratory system
Supplementary Hazards
WGK
WGK 3
Flash Point(F)
1.4 °F
Flash Point(C)
-17 °C
Regulatory Information
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Palladium-catalyzed aerobic oxidative cross-coupling reactions of terminal alkynes with alkylzinc reagents
Chen M, et al.
Journal of the American Chemical Society, 132(12), 4101-4103 (2010)
Non-peptidic small molecule inhibitors of XIAP
Park C-M, et al.
Bioorganic & Medicinal Chemistry Letters, 15(3), 771-775 (2005)
Substituted thieno [2, 3-d] pyrimidines as adenosine A2A receptor antagonists
Shook BC, et al.
Bioorganic & Medicinal Chemistry Letters, 23(9), 2688-2691 (2013)
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