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Merck
CN

495050

Luperox® DDM-9, 2-Butanone peroxide solution

~35 wt. % in 2,2,4-trimethyl-1,3-pentanediol diisobutyrate

Synonym(s):

2-Butanone peroxide solution, Methyl ethyl ketone peroxide solution

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About This Item

Linear Formula:
C2H5C(OOH)(CH3)OOC(OOH)(CH3)C2H5
CAS Number:
1338-23-4
Molecular Weight:
210.22
PubChem Substance ID:
24872944
UNSPSC Code:
12162002
Beilstein/REAXYS Number:
1759757
MDL number:
MFCD00042641

Key Documents

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SMILES string

CCC(C)(OO)OOC(C)(CC)OO

InChI

1S/C8H18O6/c1-5-7(3,11-9)13-14-8(4,6-2)12-10/h9-10H,5-6H2,1-4H3

InChI key

WFUGQJXVXHBTEM-UHFFFAOYSA-N

composition

available oxygen, 8-9%

reaction suitability

reagent type: oxidant

concentration

~35 wt. % in 2,2,4-trimethyl-1,3-pentanediol diisobutyrate

refractive index

n20/D 1.437

density

1 g/mL at 25 °C

storage temp.

2-8°C

Quality Level

100

Related Categories

Legal Information

Product of Arkema Inc.
Luperox is a registered trademark of Arkema Inc.

signalword

Danger

Hazard Classifications

Aquatic Chronic 3 - Eye Dam. 1 - Org. Perox. D - Repr. 2 - Skin Corr. 1B

Storage Class

5.2 - Organic peroxides and self-reacting hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKDB0354
MKCZ9756
MKCX7454
MKCX3488
MKCW1420

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Oesophageal stenosis in a child caused by ingestion of methyl ethyl ketone peroxide.
A Prez-Martnez et al.
European journal of pediatrics, 156(12), 976-977 (1998-02-07)
Jo-Ming Tseng et al.
Journal of hazardous materials, 142(3), 765-770 (2006-08-15)
Methyl ethyl ketone peroxide (MEKPO) is a typical organic peroxide with thermally unstable nature that has been broadly employed in the manufacturing process of acrylic resins, as a hardening agent for fiberglass-reinforced plastics, and as a curing agent for unsaturated
F T Fraunfelder et al.
American journal of ophthalmology, 110(6), 635-640 (1990-12-15)
Methyl ethyl ketone peroxide is a commonly used catalyst in various industries. We studied 19 eyes with a single exposure to methyl ethyl ketone peroxide that developed clinical patterns of mild injury, moderate injury, severe injury, or delayed keratitis. Delayed
M Ando et al.
Toxicology and applied pharmacology, 81(3 Pt 1), 517-524 (1985-12-01)
Some new aspects of damage to cytochrome P-450 peroxidase activities by a toxic peroxide were investigated. Methyl ethyl ketone peroxide (MEKP) damage to cytochrome P-450 and inhibition of cytochrome P-450-mediated peroxidase activities were studied. In vivo, hepatic microsomal NADH- and
P J Karhunen et al.
Human & experimental toxicology, 9(3), 197-200 (1990-05-01)
Fatal massive peripheral zonal hepatic necrosis developed in a 47-year-old man who accidentally ingested a solution of methyl ethyl ketone peroxide (MEKP) in dimethyl phthalate. Such solutions contain about 10% active oxygen. The clinical course was characterized by temporary cardiac
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