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Sigma-Aldrich

Germanium(IV) oxide

≥99.99% trace metals basis

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Synonym(s):
Germanium dioxide
Linear Formula:
GeO2
CAS Number:
1310-53-8
Molecular Weight:
104.64
EC Number:
215-180-8
MDL number:
MFCD00011030
UNSPSC Code:
12352300
PubChem Substance ID:
24871912
NACRES:
NA.23

Quality Level

100

Assay

≥99.99% trace metals basis

form

powder

mp

>400 °C (lit.)

solubility

ethylene glycol: soluble

density

4.23 g/cm3

application(s)

battery manufacturing

SMILES string

O=[Ge]=O

InChI

1S/GeO2/c2-1-3

InChI key

YBMRDBCBODYGJE-UHFFFAOYSA-N

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General description

Germanium(VI) oxide, also known as germania or germanium dioxide, is a white or off-white powder. It is a refractory metal oxide with a high melting point (1,600 °C) and offers excellent chemical resistance. In addition, germanium(VI) oxide has excellent optoelectronic properties that have made it a valuable material in the semiconducting industry. It has a high refractive index of approximately 2.1, which is higher than that of many other semiconductor materials, and a low absorption coefficient. These properties make it useful for applications such as waveguides, antireflective coatings, and high-index contrast coatings. In addition, germanium(VI) has a high bandgap of about 3.1 eV coupled with relatively high transparency in the infrared region of the electromagnetic spectrum, which makes it useful for applications such as infrared detectors, LEDs, and solar cells.

Application

Building block for inorganic nanowires. Used in the synthesis of ultra-high refractive index and ultra-low loss optical waveguides.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302

Precautionary Statements

P264 - P270 - P301 + P312 - P501

Hazard Classifications

Acute Tox. 4 Oral

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Jie Liang et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 23(71), 17879-17884 (2017-11-10)
The attractive properties of layered inorganic materials, which make them suitable for numerous applications in chemical industries and life sciences, originated from their crystalline framework structures. Here, we report a new layered germanate PKU-21, which was prepared by the hydrothermal
Rao, C.N.R., et al.
Journal of Materials Chemistry, 14, 440-440 (2004)
V V Dvoyrin et al.
Optics express, 19(9), 7992-7999 (2011-06-07)
A novel all-fiber laser based on a highly GeO2-doped dispersion-shifted Tm-codoped fiber, pumped at 1.56 µm wavelength and lasing at 1.862 µm wavelength with a slope efficiency up to 37% was demonstrated. The single-mode Tm-doped fiber with the 55GeO2-45SiO2 core
M Gunji et al.
Nanotechnology, 23(38), 385603-385603 (2012-09-06)
We report on the directed synthesis of germanium oxide (GeO(x)) nanowires (NWs) by locally catalyzed thermal oxidation of aligned arrays of gold catalyst-tipped germanium NWs. During oxygen anneals conducted above the Au-Ge binary eutectic temperature (T > 361 °C), one-dimensional
Xin-ben Zhang et al.
Optics express, 20(18), 19799-19805 (2012-10-06)
A GeO2 doped triangular-core photonic-crystal fiber (PCF) is designed and fabricated to allow the generation of a hollow beam through a nonlinear-optical transformation by femtosecond pulses at 1040 nm from a high power Yb-doped PCF laser oscillator. The hollow beam
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