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Merck
CN

483702

Germanium(IV) oxide

≥99.99% trace metals basis

Synonym(s):

Germania, Germanium oxide, Germanium dioxide

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About This Item

Linear Formula:
GeO2
CAS Number:
Molecular Weight:
104.64
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352303
EC Number:
215-180-8
MDL number:
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Product Name

Germanium(IV) oxide, ≥99.99% trace metals basis

InChI key

YBMRDBCBODYGJE-UHFFFAOYSA-N

InChI

1S/GeO2/c2-1-3

SMILES string

O=[Ge]=O

assay

≥99.99% trace metals basis

form

powder

mp

>400 °C (lit.)

solubility

ethylene glycol: soluble

density

4.23 g/cm3

application(s)

battery manufacturing

Quality Level

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Application

Building block for inorganic nanowires. Used in the synthesis of ultra-high refractive index and ultra-low loss optical waveguides.

General description

Germanium(VI) oxide, also known as germania or germanium dioxide, is a white or off-white powder. It is a refractory metal oxide with a high melting point (1,600 °C) and offers excellent chemical resistance. In addition, germanium(VI) oxide has excellent optoelectronic properties that have made it a valuable material in the semiconducting industry. It has a high refractive index of approximately 2.1, which is higher than that of many other semiconductor materials, and a low absorption coefficient. These properties make it useful for applications such as waveguides, antireflective coatings, and high-index contrast coatings. In addition, germanium(VI) has a high bandgap of about 3.1 eV coupled with relatively high transparency in the infrared region of the electromagnetic spectrum, which makes it useful for applications such as infrared detectors, LEDs, and solar cells.

wgk

WGK 3

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral

Storage Class

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


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Jie Liang et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 23(71), 17879-17884 (2017-11-10)
The attractive properties of layered inorganic materials, which make them suitable for numerous applications in chemical industries and life sciences, originated from their crystalline framework structures. Here, we report a new layered germanate PKU-21, which was prepared by the hydrothermal
Imoto, K.
Optronics, 260, 116-116 (2003)
Rao, C.N.R., et al.
Journal of Materials Chemistry, 14, 440-440 (2004)
V V Dvoyrin et al.
Optics express, 19(9), 7992-7999 (2011-06-07)
A novel all-fiber laser based on a highly GeO2-doped dispersion-shifted Tm-codoped fiber, pumped at 1.56 µm wavelength and lasing at 1.862 µm wavelength with a slope efficiency up to 37% was demonstrated. The single-mode Tm-doped fiber with the 55GeO2-45SiO2 core
Xin-ben Zhang et al.
Optics express, 20(18), 19799-19805 (2012-10-06)
A GeO2 doped triangular-core photonic-crystal fiber (PCF) is designed and fabricated to allow the generation of a hollow beam through a nonlinear-optical transformation by femtosecond pulses at 1040 nm from a high power Yb-doped PCF laser oscillator. The hollow beam

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