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Merck
CN

482307

Silver trifluoroacetate

≥99.99% trace metals basis

Synonym(s):

Trifluoroacetic acid silver salt

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About This Item

Linear Formula:
CF3COOAg
CAS Number:
Molecular Weight:
220.88
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
EC Number:
221-004-0
Beilstein/REAXYS Number:
3634022
MDL number:
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Product Name

Silver trifluoroacetate, ≥99.99% trace metals basis

InChI key

KZJPVUDYAMEDRM-UHFFFAOYSA-M

InChI

1S/C2HF3O2.Ag/c3-2(4,5)1(6)7;/h(H,6,7);/q;+1/p-1

SMILES string

FC(F)(F)C(=O)O[Ag]

assay

≥99.99% trace metals basis

form

crystalline powder
powder, crystals or chunks

reaction suitability

core: silver

mp

257-260 °C (dec.) (lit.)

Quality Level

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Application

Silver trifluoroacetate can be used:
  • As a precursor to synthesize silver nanoparticles.
  • As a starting material to fabricate conducting silver networks with high transmittance and low resistance via a polymer-assisted electrospinning technique.
  • As a reagent to prepare polynuclear luminescent complexes.
  • As a bifunctional reagent for oxidative carbonylative [4 + 1] annulation of aromatic acid.

General description

Silver trifluoroacetate is a versatile reagent used in organic synthetic reactions, including acylation, alkylation, and cyclization reactions. It is also used to fabricate silver nanomaterials.

pictograms

Skull and crossbonesEnvironment

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Perhalophenyl(tetrahydrothiophene)gold(I) Complexes as Lewis Bases in Acid?Base Reactions with Silver Trifluoroacetate
Eduardo J. Fernandez, et al.},
Organometallics, 26, 5931-5939 (2007)
Direct Synthesis of Narrowly Dispersed Silver Nanoparticles Using a Single-Source Precursor
Xue Zhang Lin, et al.
Langmuir, 19, 10081-10085 (2003)
Silver trifluoroacetate as a bifunctional reagent for palladium-catalyzed oxidative carbonylative [4+ 1] annulation of aromatic acids
Zhuang-Zhuang Li, et al
Organic Chemistry Frontiers : An International Journal of Organic Chemistry / Royal Society of Chemistry, 10, 2243-2250 (2023)
Conducting Silver Networks Based on Electrospun Poly(Methyl Methacrylate) and Silver Trifluoroacetate
Hung-Tao Chen, et al.
ACS Applied Materials & Interfaces, 7, 9479-9485 (2015)

Articles

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